1,4,5,8-tetrakis(4-methoxyphenyl)-9,10-anthracenedione

Base Information

• Chemical Name: 1,4,5,8-tetrakis(4-methoxyphenyl)-9,10-anthracenedione
• CAS No.: 1149379-24-7
• Molecular Formula: C₄₂H₃₂O₆
• Molecular Weight: 632.712
• Mol file: 1149379-24-7.mol

Synonyms:1,4,5,8-tetrakis(4-methoxyphenyl)-9,10-anthracenedione

Chemical Property of 1,4,5,8-tetrakis(4-methoxyphenyl)-9,10-anthracenedione

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of 1,4,5,8-tetrakis(4-methoxyphenyl)-9,10-anthracenedione

There total 2 articles about 1,4,5,8-tetrakis(4-methoxyphenyl)-9,10-anthracenedione which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 72.0%

1,4-dibromo-5,8-dichloroanthraquinone (500798-34-5) + 4-methoxyphenylboronic acid (5720-07-0) → 1,4,5,8-tetrakis(4-methoxyphenyl)-9,10-anthracenedione (1149379-24-7)

Guidance literature:

With bis-triphenylphosphine-palladium(II) chloride; sodium carbonate; triphenylphosphine; In 1,2-dimethoxyethane; water; at 65 ℃; for 18h; Inert atmosphere;

DOI:10.3390/molecules14031013

Reference yield: 72.0%

1,4,5,8-tetrachloroanthraquinone (81-58-3) + 4-methoxyphenylboronic acid (5720-07-0) → 1,4,5,8-tetrakis(4-methoxyphenyl)-9,10-anthracenedione (1149379-24-7)

Guidance literature:

With tetrakis(triphenylphosphine) palladium⁽⁰⁾; sodium carbonate; In 1,2-dimethoxyethane; water; at 70 ℃; for 18h; Inert atmosphere;

DOI:10.3184/030823409X12586584303880

upstream raw materials:

1,4-dibromo-5,8-dichloroanthraquinone

4-methoxyphenylboronic acid

1,4,5,8-tetrachloroanthraquinone

Refernces

• 1、 Thiemann, Thies,Tanaka, Yasuko,Iniesta, Jesus,Varghese, H. Tresa,Pannicker, C. Yohannan. "Arylation of chloroanthraquinones by surprisingly facile Suzuki-Miyaura cross-coupling reactions". experimental part. p. 732 - 736. Retrieved 2010/03/24.