Triethylsulfonium Bis(trifluoromethanesulfonyl)imide

Base Information

• Chemical Name: Triethylsulfonium Bis(trifluoromethanesulfonyl)imide
• CAS No.: 321746-49-0
• Molecular Formula: C₂F₆NO₄S₂*C₆H₁₅S
• Molecular Weight: 399.4
• Hs Code.: 29350090
• European Community (EC) Number: 628-992-6
• UNII: BQ6SR432FE
• ChEMBL ID: CHEMBL3186996
• DSSTox Substance ID: DTXSID4047888
• Mol file: 321746-49-0.mol

Synonyms:321746-49-0;Triethylsulfonium bis(trifluoromethylsulfonyl)imide;Triethylsulfonium Bis(trifluoromethanesulfonyl)imide;BQ6SR432FE;DTXSID4047888;bis(trifluoromethylsulfonyl)azanide;triethylsulfanium;Triethylsulfonium bis(trifluoromethanesulfonylamide);TRIETHYLSULFONIUMBIS(TRIFLUOROMETHANESULFONYL)IMIDE;Sulfonium, triethyl-, salt with 1,1,1-Trifluoro-N-((trifluoromethyl)sulfonyl)methanesulfonamide (1:1);[SEt3]NTf2;UNII-BQ6SR432FE;CHEMBL3186996;DTXCID4027864;Tox21_200552;MFCD08276438;NCGC00248742-01;NCGC00258106-01;CAS-321746-49-0;CS-0378516;T2314;D92596;Triethylsulfonium Bis((trifluoromethylsulfonyl)amide;Triethylsulphonium bis(trifluoromethylsulphonyl)Imide, for electrochemistry;Triethylsulfonium bis(trifluoromethylsulfonyl)imide, for electrochemistry, >=95.0% (qNMR)

Chemical Property of Triethylsulfonium Bis(trifluoromethanesulfonyl)imide

Chemical Property:

• Refractive Index: 1.4260 to 1.4300
• PSA: 110.34000
• Density: 1.47 g/cm³
• LogP: 4.88530
• Water Solubility.: Insoluble in water
• Hydrogen Bond Donor Count: 0
• Hydrogen Bond Acceptor Count: 11
• Rotatable Bond Count: 5
• Exact Mass: 399.00674045
• Heavy Atom Count: 22
• Complexity: 399

Purity/Quality:

98%,99%, ^*data from raw suppliers

Triethylsulfonium bis(trifluoromethylsulfonyl)imide ^*data from reagent suppliers

Safty Information:

• Pictogram(s): Xi
• Hazard Codes: Xi
• Statements: 36/37/38
• Safety Statements: 26

MSDS Files:

SDS file from LookChem

Useful:

• Canonical SMILES: CC[S+](CC)CC.C(F)(F)(F)S(=O)(=O)[N-]S(=O)(=O)C(F)(F)F
• Uses: Triethylsulfonium bis(trifluoromethylsulfonyl)imide is a room-temperature?ionic liquid?(RTIL ) that can be used:As an electrolyte in electrochemical double-layer supercapacitors.As a model ionic liquid used in the studies of structure effect of ions on electrochemical windows (EWs).As a component of the gel polymer electrolyte, which is used in the construction of symmetrical electrical-double layer?capacitors.As an electrolyte in the in-plane supercapacitor devices.

Technology Process of Triethylsulfonium Bis(trifluoromethanesulfonyl)imide

There total 2 articles about Triethylsulfonium Bis(trifluoromethanesulfonyl)imide which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 70.0%

triethylsulfonium iodide (1829-92-1) + bis(trifluoromethane)sulfonimide lithium (90076-65-6) → triethylsulfonium bis(trifluoromethylsulfonyl)imide (321746-49-0)

Guidance literature:

In water;

DOI:10.1246/cl.2000.1430

Reference yield:

diethyl sulfate (64-67-5) + diethyl sulphide (352-93-2) + bis(trifluoromethane)sulfonimide lithium (90076-65-6) → triethylsulfonium bis(trifluoromethylsulfonyl)imide (321746-49-0)

Guidance literature:

diethyl sulfate; diethyl sulphide; In dichloromethane; water; for 12h; Heating;

bis(trifluoromethane)sulfonimide lithium; In dichloromethane; water; at 20 ℃; for 1h; Further stages.;

DOI:10.1002/anie.200700941

upstream raw materials:

triethylsulfonium iodide

bis(trifluoromethane)sulfonimide lithium

diethyl sulfate

diethyl sulphide

Refernces

• 1、 Slattery, John M.,Daguenet, Corinne,Dyson, Paul J.,Schubert, Thomas J. S.,Krossing, Ingo. "How to predict the physical properties of ionic liquids: A volume-based approach". . p. 5384 - 5388. Retrieved 2008/03/15.