Technology Process of 2-(6-chloro-4'-(ethylsulfonyl)-2'-methoxy-[1,1'-biphenyl]-3-yl)-4,4,5,5-tetramethyl-1,3,2-dioxaborolane
There total 13 articles about 2-(6-chloro-4'-(ethylsulfonyl)-2'-methoxy-[1,1'-biphenyl]-3-yl)-4,4,5,5-tetramethyl-1,3,2-dioxaborolane which
guide to synthetic route it.
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synthetic route:
- Guidance literature:
-
With
(1,1'-bis(diphenylphosphino)ferrocene)palladium(II) dichloride; potassium acetate;
In
1,4-dioxane;
at 80 ℃;
for 2h;
Inert atmosphere;
- Guidance literature:
-
Multi-step reaction with 2 steps
1: 2,6-dimethylpyridine / dichloromethane / 2 h / 20 °C
2: (1,1'-bis(diphenylphosphino)ferrocene)palladium(II) dichloride; potassium acetate / 1,4-dioxane / 2 h / 80 °C / Inert atmosphere
With
2,6-dimethylpyridine; (1,1'-bis(diphenylphosphino)ferrocene)palladium(II) dichloride; potassium acetate;
In
1,4-dioxane; dichloromethane;
- Guidance literature:
-
Multi-step reaction with 6 steps
1: methanol / 12 h / 100 °C / Sealed tube
2: (1,1'-bis(diphenylphosphino)ferrocene)palladium(II) dichloride; potassium acetate / 1,4-dioxane / 18 h / 100 °C / Inert atmosphere
3: caesium carbonate; (1,1'-bis(diphenylphosphino)ferrocene)palladium(II) dichloride / water / 3 h / 100 °C
4: hydrogenchloride / 1,4-dioxane / 40 h / 20 °C
5: 2,6-dimethylpyridine / dichloromethane / 2 h / 20 °C
6: (1,1'-bis(diphenylphosphino)ferrocene)palladium(II) dichloride; potassium acetate / 1,4-dioxane / 2 h / 80 °C / Inert atmosphere
With
2,6-dimethylpyridine; hydrogenchloride; (1,1'-bis(diphenylphosphino)ferrocene)palladium(II) dichloride; potassium acetate; caesium carbonate;
In
1,4-dioxane; methanol; dichloromethane; water;