Vinyl-t-butyldimethylsilane

Base Information

• Chemical Name: Vinyl-t-butyldimethylsilane
• CAS No.: 24858-02-4
• Molecular Formula: C8H18Si
• Molecular Weight: 142.314
• Mol file: 24858-02-4.mol

Synonyms:Silane, (1,1-dimethylethyl)ethenyldimethyl-;

Chemical Property of Vinyl-t-butyldimethylsilane

Chemical Property:

• Vapor Pressure: 12.796mmHg at 25°C
• Refractive Index: 1.4281
• Boiling Point: 128.725 °C at 760 mmHg
• Flash Point: 16.564 °C
• PSA: 0.00000
• Density: 0.743 g/cm³
• LogP: 3.22010

Purity/Quality:

99.5% ^*data from raw suppliers

VINYL-TERT-BUTYLDIMETHYLSILANE 95.00% ^*data from reagent suppliers

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

Technology Process of Vinyl-t-butyldimethylsilane

There total 5 articles about Vinyl-t-butyldimethylsilane which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

tert-butyldimethylfluorosilane (2357-76-8) + vinylmagnesium chloride (3536-96-7) → vinyl(tert-butyl)dimethylsilane (24858-02-4)

Guidance literature:

In tetrahydrofuran; Heating;

DOI:10.1016/S0022-328X(00)80203-X

Reference yield:

Vinyl bromide (593-60-2,25951-54-6) + tert-butyldimethylsilyl chloride (18162-48-6) → vinyl(tert-butyl)dimethylsilane (24858-02-4)

Guidance literature:

In tetrahydrofuran; diethyl ether; pentane; for 96h; Yield given; Ambient temperature;

DOI:10.1039/ft9949003383

Reference yield:

vinylmagnesium chloride (3536-96-7) + tert-butyldimethylsilyl chloride (18162-48-6) → vinyl(tert-butyl)dimethylsilane (24858-02-4)

Guidance literature:

DOI:10.1021/jo01258a052

upstream raw materials:

tert-butyldimethylfluorosilane

vinylmagnesium chloride

tert-butyldimethylsilyl chloride

vinyllithium

Downstream raw materials:

2-(tert-butyldimethylsilyl)ethyl-4'-bromophenyl sulfide

methyl 4-(E-2-(tert-butyldimethylsilyl)vinyl)benzoate

4-(trimethylsilyl)benzoic acid methyl ester

4-{4-[2-(tert-Butyl-dimethyl-silanyl)-ethylsulfanyl]-phenylethynyl}-2-methyl-1-trimethylsilanylethynyl-benzene

Refernces

• 1、 Werstiuk, Nick H.,Ma, Jiangong,McAllister, Michael A.,Tidwell, Thomas T.,Zhao, Da-chuan. "Conformation Properties of Buta-1,3-diene-1,4-diones (Bisketenes): Computational and Photoelectron Spectroscopic Studies". . p. 3383 - 3390. Retrieved 1994.
• 2、 Cunico, Robert F.. "THE SILAPINACOL REARRANGEMENT: CONVERSION OF α,β-DIHYDROXYSILANES INTO α-SILYL CARBONYL COMPOUNDS". . p. 4269 - 4272. Retrieved 2007/10/02.