hydroxytrimethylsilane

Base Information

• Chemical Name: hydroxytrimethylsilane
• CAS No.: 1066-40-6
• Molecular Formula: C3H10 O Si
• Molecular Weight: 90.1973
• Hs Code.: 29319090
• European Community (EC) Number: 213-914-1
• UNII: Z4BIN3300P
• DSSTox Substance ID: DTXSID7061433
• Nikkaji Number: J555J
• Wikipedia: Trimethylsilanol
• Wikidata: Q416218
• ChEMBL ID: CHEMBL4238997
• Mol file: 1066-40-6.mol

Synonyms:Silanol,trimethyl- (6CI,8CI,9CI); Hydroxytrimethylsilane; Trimethylhydroxysilane;Trimethylsilanol; Trimethylsilyl alcohol

Chemical Property of hydroxytrimethylsilane

Chemical Property:

• Vapor Pressure: 73.9mmHg at 25°C
• Melting Point: -4.5 °C
• Refractive Index: 1.3889
• Boiling Point: 75°Cat760mmHg
• PKA: 12.67±0.58(Predicted)
• Flash Point: °C
• PSA: 20.23000
• Density: 0.81g/cm³
• LogP: 0.81360
• Storage Temp.: Sealed in dry,Store in freezer, under -20°C
• Water Solubility.: Soluble in water (1.00 mg/ml).
• Hydrogen Bond Donor Count: 1
• Hydrogen Bond Acceptor Count: 1
• Rotatable Bond Count: 0
• Exact Mass: 90.050091473
• Heavy Atom Count: 5
• Complexity: 28.4

Purity/Quality:

98% ^*data from raw suppliers

Trimethylsilanol ^*data from reagent suppliers

Safty Information:

• Pictogram(s): F
• Hazard Codes: F
• Statements: 11

MSDS Files:

SDS file from LookChem

Useful:

• Chemical Classes: Metals -> Metalloid Compounds (Silicon)
• Canonical SMILES: C[Si](C)(C)O
• Uses: Trimethylsilanol used as a hydrophobic coat on silicate surfaces. Used as an as an antimicrobial agent.

Technology Process of hydroxytrimethylsilane

There total 169 articles about hydroxytrimethylsilane which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 98.0%

N-trimethylsilylaniline (3768-55-6) → Trimethylsilanol (1066-40-6) + benzenediazonium tetrafluoroborate (369-57-3)

Guidance literature:

With nitrosonium tetrafluoroborate; In dichloromethane; Ambient temperature;

Reference yield: 96.0%

N-trimethylsilylaniline (3768-55-6) → Trimethylsilanol (1066-40-6) + benzene diazonium chloride (100-34-5)

Guidance literature:

With nitrosylchloride; In dichloromethane; for 0.166667h; Ambient temperature;

Reference yield: 82.0%

4-Nitro-N-(trimethylsilyl)anilin (63911-89-7) → Trimethylsilanol (1066-40-6) + trimethyl(isopentyloxy)silane (18246-56-5) + 4-nitrobenzenediazonium chloride (100-05-0)

Guidance literature:

With chloro-trimethyl-silane; isopentyl nitrite; In dichloromethane; for 10h; Ambient temperature;

upstream raw materials:

diethyl ether

bis(trimethylsilyl)sulphate

1-methyl-4-nitrosobenzene

trimethylsilyl fluoride

Downstream raw materials:

Hexamethyldisiloxane

diethyl trimethylsilyl phosphite

1,1,1,3,3-pentamethyl-1,3-disiloxane

Phenylborsaeure-bis-trimethylsilylester

Refernces

• 1、 Hoffmeyer, H.,Potzinger, P.,Reimann, B.. "Reaction of O(3P) with Hexamethyldisilane". . p. 4829 - 4831. Retrieved 1985.
• 2、 Ivanov, P. V.,Maslova, V. I.,Mlakhovskaya, O. V.,Chernyshev, E. A.. "The role of the phase quasiequilibrium in the reaction system chlorotriorganosilane-water-acetone". . p. 1156 - 1160. Retrieved 1994.
• 3、 Gusel'nikov,Flowers. "". . p. 864. Retrieved 1967.
• 4、 Fajgar, Radek,Pola, Josef. "Trimethylsilyl group migration in the Criegee intermediate of gas-phase ozonolysis of trimethylsilylethenes". . p. 2435 - 2438. Retrieved 2000.
• 5、 Davis, Dennis D.,Jacocks, Henry M.. "DEOXYMETALATION REACTIONS. THE MECHANISMS OF DEOXYSILYLATION OF MONO-TRIMETHYLSILYL-AND BIS-TRIMETHYLSILYL-SUBSTITUTED ALCOHOLS AND A COMPARISON TO THE MECHANISM OF DEOXYSTANNYLATION AND DEOXYPLUMBYLATION". . p. 33 - 47. Retrieved 1981.
• 6、 Migulin, Dmitry,Milenin, Sergey,Cherkaev, Georgy,Svidchenko, Evgeniya,Surin, Nikolay,Muzafarov, Aziz. "Sodiumoxy(aminopropyl)alkoxysilanes - AB2 type monomers for the synthesis of hyperbranched poly(aminopropyl)alkoxysiloxanes and their derivatives". . p. 24 - 32. Retrieved 2018.
• 7、 Kohlheim,Lange,Kelling. "On the reaction of silanols with alcohols". . p. 660 - 662. Retrieved 1996.
• 8、 Shi, Min,Nicholas, Kenneth M.. "Catalytic Dehydrocoupling of Silane by a Homogenous Rhodium Complex with Water". . p. 400 - 401. Retrieved 1997.
• 9、 Bennett, D. W.,Spicer, L. D.. "The Reaction between Sulfur Dioxide and Hexamethyldisilazane. 3. The Characterization of Ammonium (Trimethylsilyl)sulfite". . p. 5522 - 5526. Retrieved 1981.
• 10、 Vvedenskii,Shtefan,Malyushenko,Shilkin. "2-Selenophenethiol and 5-methylthio-2-selenophenethiol: Synthesis and autoconversions". . p. 426 - 428. Retrieved 1997.