Hexadecanoic-d31 acid

Base Information

• Chemical Name: Hexadecanoic-d31 acid
• CAS No.: 39756-30-4
• Molecular Formula: C16HD31O2
• Molecular Weight: 287.62
• Mol file: 39756-30-4.mol

Synonyms:HEXADECANOIC-D31 ACID;HEXADECANOIC-D ACID;PALMITIC-D 31 ACID;PALMITIC ACID (D31);PALMITIC-D31 ACID, 98 ATOM % D;hexadecanoic-d=;Hexadecanoic Acid-D31

Chemical Property of Hexadecanoic-d31 acid

Chemical Property:

• Vapor Pressure: 3.28E-05mmHg at 25°C
• Melting Point: 61-64 °C(lit.)
• Refractive Index: 1.453
• Boiling Point: 340.6 °C at 760 mmHg
• Flash Point: 154.1 °C
• PSA: 37.30000
• Density: 1.001 g/cm³
• LogP: 5.55230
• Storage Temp.: Room Temperature
• Solubility.: Chloroform (Slightly), DMSO (Slightly), Methanol (Slightly)

Purity/Quality:

99% ^*data from raw suppliers

Palmitic Acid-d31 ^*data from reagent suppliers

Safty Information:

• Pictogram(s): Xi
• Hazard Codes: Xi
• Statements: 36/37/38
• Safety Statements: 26-36

MSDS Files:

SDS file from LookChem

Useful:

• Uses: Palmitic Acid-d31 is the isotope labelled analog of Palmitic Acid (P144500); a common fatty acid found in plants and animals. The body converts excess carbohydrates into Palmitic Acid, thus Palmitic Acid is the first fatty acid produced during fatty acid synthesis as well as a precursor for longer fatty acids.

Technology Process of Hexadecanoic-d31 acid

There total 3 articles about Hexadecanoic-d31 acid which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 99.0%

1-hexadecylcarboxylic acid (57-10-3) → palmitic acid-d31 (39756-30-4,272442-14-5,285979-77-3,358730-99-1,78387-70-9,1219802-61-5)

Guidance literature:

1-hexadecylcarboxylic acid; With d8-isopropanol; 10% Pt/activated carbon; water-d2; at 120 ℃; for 24h;

With water; sodium hydroxide; at 70 ℃; for 24h; Reagent/catalyst;

DOI:10.1002/adsc.201600363

Reference yield:

β-lactoglobulin palmitic acid-2,2,3,3,4,4,5,5,6,6,7,7,8,8,9,9,10,10,11,11,12,12,13,13,14,14,15,15,16,16,16-d31 1:1 complex → palmitic acid-d31 (39756-30-4,272442-14-5,285979-77-3,358730-99-1,78387-70-9,1219802-61-5) + β-lactoglobulin

Guidance literature:

In methanol; at 25 ℃; pH=8; Temperature; Time; Kinetics; aq. buffer;

DOI:10.1021/ja300092w

Reference yield:

→ palmitic acid-d31 (39756-30-4,272442-14-5,285979-77-3,358730-99-1,78387-70-9,1219802-61-5)

Guidance literature:

upstream raw materials:

1-hexadecylcarboxylic acid

Downstream raw materials:

methyl hexadecanoate-d31

1-hexadecyl-d33-ol

tripalmitin-d₉₃

palmitic acid-d31 glycidyl ester

Refernces

• 1、 Liu, Lan,Michelsen, Klaus,Kitova, Elena N.,Schnier, Paul D.,Brown, Alex,Klassen, John S.. "Deuterium kinetic isotope effects on the dissociation of a protein-fatty acid complex in the gas phase". supporting information; scheme or table. p. 5931 - 5937. Retrieved 2012/05/07.