YTTERBIUM(III) CHLORIDE HEXAHYDRATE

Base Information

• Chemical Name: YTTERBIUM(III) CHLORIDE HEXAHYDRATE
• CAS No.: 10035-01-5
• Molecular Formula: Cl₃Yb*3H₂O
• Molecular Weight: 333.445
• Hs Code.: 28273990
• Mol file: 10035-01-5.mol

Synonyms:Ytterbiumtrichloride hexahydrate;ytterbium(+2) cation trichloride hexahydrate;

Chemical Property of YTTERBIUM(III) CHLORIDE HEXAHYDRATE

Chemical Property:

• Appearance/Colour: solid
• Melting Point: 180 °C (dec.)(lit.)
• PSA: 55.38000
• Density: 2.58 g/mL at 25 °C(lit.)
• LogP: 1.68270
• Storage Temp.: Inert atmosphere,Room Temperature
• Water Solubility.: very soluble H2O [HAW93]

Purity/Quality:

98%,99%, ^*data from raw suppliers

Ytterbium(III) chloride hexahydrate (99.9%-Yb) (REO) ^*data from reagent suppliers

Safty Information:

• Pictogram(s): Xi
• Hazard Codes: Xi
• Statements: 36/37/38
• Safety Statements: 26-36

MSDS Files:

SDS file from LookChem

Total 1 MSDS from other Authors

Useful:

• Description: Ytterbium (III) chloride hexahydrate is a stable, hygroscopic (absorbs moisture from the air), moisture-sensitive compound. It is incompatible with strong oxidising agents. Exposure to ytterbium (III) chloride hexahydrate has been reported to cause eye irritation, skin irritation, and respiratory tract irritation.
• Uses: Ytterbium(III) chloride hexahydrate can be used in applications such as: rare earth doping of yttrium oxide (Y2O3) nanoparticles for the development of fluorescent materials, doping of yttrium fluoride (YF3) nanoparticles for potential usage in 3D displays, photovoltaics, and drug delivery

Technology Process of YTTERBIUM(III) CHLORIDE HEXAHYDRATE

There total 10 articles about YTTERBIUM(III) CHLORIDE HEXAHYDRATE which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 99.0%

hydrogenchloride (7647-01-0,15364-23-5) + ytterbium(III) oxide + water (7732-18-5) → ytterbium(III) chloride hexahydrate (10035-01-5)

Guidance literature:

In hydrogenchloride; Yb2O3 was heated with concd. aq. HCl; soln. was evapd. to dryness in vacuo at 50°C;

DOI:10.1016/j.ica.2003.11.011

Reference yield:

hydrogenchloride (7647-01-0,15364-23-5) + ytterbium(III) oxide → ytterbium(III) chloride hexahydrate (10035-01-5)

Guidance literature:

In hydrogenchloride; water; oxide dissoln. in H2O/HCl, excess water boiling off (stiring) until thick slurry obtained, slurry cooling to room temp., excess soln. filtrationoff; solid vac. treating (<1 torr) at 30-40°C (intermediate grinding and stirring);

Reference yield:

hydrogenchloride (7647-01-0,15364-23-5) + ytterbium(III) oxide → ytterbium trichloride hydrate (10035-01-5)

Guidance literature:

In hydrogenchloride; prepn. by dissolving of oxide in HCl; solvent evapd. until damp salt was obtained;

upstream raw materials:

hydrogenchloride

water

Downstream raw materials:

YbCl₃*H₂O

[5,10,15,20-tetraphenylporphinato]ytterbium(III) chloride

(YbCl₂(((H₃C)2N)3PO)4)⁽¹⁺⁾*B(C₆H₅)4^(1-)=(YbCl₂(((H₃C)2N)3PO)4)(B(C₆H₅)4)

Refernces

• 1、 Sun, Lining,Dang, Song,Yu, Jiangbo,Feng, Jing,Shi, Liyi,Zhang, Hongjie. "Near-infrared luminescence from visible-light-sensitized hybrid materials covalently linked with tris(8-hydroxyquinolinate)-lanthanide [Er(III), Nd(III), and Yb(III)] derivatives". . p. 16393 - 16397. Retrieved 2010.
• 2、 Xue, Ning,Fan, Xianping,Wang, Zhiyu,Wang, Minquan. "Synthesis process and the luminescence properties of rare earth doped NaLa(WO4)2 nanoparticles". . p. 1891 - 1896. Retrieved 2008.
• 3、 ?yszczek, Renata. "Synthesis, structure, thermal and luminescent behaviors of lanthanide-Pyridine-3,5-dicarboxylate frameworks series". . p. 120 - 127. Retrieved 2011/01/08.