METHYL PERFLUOROHEPTANOATE

Base Information

• Chemical Name: METHYL PERFLUOROHEPTANOATE
• CAS No.: 14312-89-1
• Molecular Formula: C8H3F13O2
• Molecular Weight: 378.09
• Hs Code.: 29159000
• Mol file: 14312-89-1.mol

Synonyms:Heptanoicacid, tridecafluoro-, methyl ester (8CI,9CI);Methyl perfluoroheptanoate;Methyltridecafluoroheptanoate;Tridecafluoroheptanoic acid methyl ester;

Chemical Property of METHYL PERFLUOROHEPTANOATE

Chemical Property:

• Refractive Index: 1.3022
• Boiling Point: 132.4 °C at 760 mmHg
• Flash Point: 33.8 °C
• PSA: 26.30000
• Density: 1.607 g/cm³
• LogP: 3.89820

Purity/Quality:

98%,99%, ^*data from raw suppliers

MethylPerfluoroheptanoate ^*data from reagent suppliers

Safty Information:

• Pictogram(s): F
• Hazard Codes: F

MSDS Files:

SDS file from LookChem

Useful:

Technology Process of METHYL PERFLUOROHEPTANOATE

There total 5 articles about METHYL PERFLUOROHEPTANOATE which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 88.0%

methanol (67-56-1) + perfluoroheptanoyl chloride (52447-22-0) → methyl perfluoroheptanoate (14312-89-1)

Guidance literature:

With pyridine; at 0 - 5 ℃; for 4h;

DOI:10.1016/S0022-1139(00)85181-7

Reference yield: 87.0%

methanol (67-56-1) + perfluoroheptanoic acid (375-85-9) → methyl perfluoroheptanoate (14312-89-1)

Guidance literature:

With sulfuric acid; for 4h; Heating / reflux;

Reference yield: 82.0%

methanol (67-56-1) + perfluorooct-1-ene (559-14-8) → methyl perfluoroheptanoate (14312-89-1)

Guidance literature:

With oxygen; ozone; In 1,1,2-Trichloro-1,2,2-trifluoroethane; at 0 - 5 ℃; for 2h;

DOI:10.1023/A:1012311903712

upstream raw materials:

methanol

perfluoroheptanoyl chloride

perfluorooct-1-ene

perfluoroheptanoic acid

Downstream raw materials:

perfluoroheptanoic acid sodium salt

N-hydroxybenzenecarboximidamide

diethyl 2-[2,2,3,3,4,4,5,5,6,6,7,7,7-tridecafluoro-1-(2-phenylhydrazino)heptyl]malonate

2,2,3,3,4,4,5,5,6,6,7,7,7-tridecafluoroheptan-1-ol

Refernces

• 1、 Odinokov,Akhmetova,Bazunova,Savchenko,Paramonov,Khalilov. "Ozonolysis of alkenes and studies of reactions of polyfunctional compounds: LXV.* Ozonolysis of perfluoro-1-octene in Freon-113". . p. 321 - 325. Retrieved 2001.