BIS(2-HYDROXYETHYL THIOETHYL)ETHER

Base Information

• Chemical Name: BIS(2-HYDROXYETHYL THIOETHYL)ETHER
• CAS No.: 7426-02-0
• Molecular Formula: C8H18O3S2
• Molecular Weight: 226.361
• Mol file: 7426-02-0.mol

Synonyms:Ethanol,2,2'-[oxybis(ethylenethio)]di- (7CI,8CI);1,11-Dihydroxy-6-oxa-3,9-dithiaundecane;2,2'-[Oxybis(ethylenethio)]diethanol;6-Oxa-3,9-dithiaundecane-1,11-diol;b,b'-Bis(hydroxyethylthio)ethyl ether;

Chemical Property of BIS(2-HYDROXYETHYL THIOETHYL)ETHER

Chemical Property:

• Boiling Point: 343.5 °C at 760 mmHg
• Flash Point: 161.5 °C
• PSA: 100.29000
• Density: 1.187 g/cm³
• LogP: 0.45400

Purity/Quality:

99% ^*data from raw suppliers

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

Technology Process of BIS(2-HYDROXYETHYL THIOETHYL)ETHER

There total 1 articles about BIS(2-HYDROXYETHYL THIOETHYL)ETHER which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

bis (2-chloroethyl) sulphide (505-60-2) → 2,2'-thiobis-ethanol (111-48-8) + 6,12,18,24-tetraoxa-3,9,15,21,27-pentathia-nonacosane-1,29-diol (121262-73-5) + 2,2'-bis(2-hydroxyethylsulfanyl)diethyl ether (7426-02-0) + 6,12-dioxa-3,9,15-trithia-heptadecane-1,17-diol (86218-79-3) + 6,12,18-trioxa-3,9,15,21-tetrathia-tricosane-1,23-diol (86164-05-8) + 6,12,18,24,30-pentaoxa-3,9,15,21,27,33-hexathia-pentatriacontane-1,35-diol (121262-74-6) + C10H21ClO3S2 (208517-90-2) + C28H58O8S7 (121262-75-7)

Guidance literature:

With KF/Al₂O₃; water;

DOI:10.1021/jo901713c

Reference yield: 86.0%

2,2'-bis(2-hydroxyethylsulfanyl)diethyl ether (7426-02-0) → 2,2'-bis(2-hydroxyethylsulfinyl)diethyl ether (167940-02-5)

Guidance literature:

With sodium periodate; In methanol; at 20 ℃; for 14h;

DOI:10.1080/10426500390228710

Reference yield: 72.0%

2,2'-bis(2-hydroxyethylsulfanyl)diethyl ether (7426-02-0) → bis(2-chloroethylthioethyl)ether (63918-89-8)

Guidance literature:

With thionyl chloride; In dichloromethane; at 0 - 20 ℃; for 1h; Inert atmosphere; Schlenk technique;

DOI:10.1021/acs.joc.8b01670

upstream raw materials:

bis (2-chloroethyl) sulphide

Downstream raw materials:

bis(2-bromoethyl)sulfide

bis(2-chloroethylthioethyl)ether

3,9,15-trioxa-6,12-dithia-1(2,6)-pyridina-cyclohexadecaphane-2,16-dione

3,9,15-trioxa-6,12-dithia-1(3,5)-pyridina-cyclohexadecaphane-2,16-dione

Refernces