Mercury, chloro(cyclohexyl)

Base Information

• Chemical Name: Mercury, chloro(cyclohexyl)
• CAS No.: 24371-94-6
• Molecular Formula: C6H11ClHg
• Molecular Weight: 319.196
• Hs Code.: 2931900090
• Mol file: 24371-94-6.mol

Synonyms:Cyclohexylmercurychloride (6CI);Chlorocyclohexylmercury;Cyclohexylmercuric chloride;chloro(cyclohexyl)mercury;

Chemical Property of Mercury, chloro(cyclohexyl)

Chemical Property:

• Melting Point: 163-164 °C
• PSA: 0.00000
• LogP: -0.84370

Purity/Quality:

99% ^*data from raw suppliers

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

Technology Process of Mercury, chloro(cyclohexyl)

There total 3 articles about Mercury, chloro(cyclohexyl) which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

mercury dichloride → cyclohexylmercury chloride (24371-94-6)

Guidance literature:

With acetic acid; sodium chloride; In tetrahydrofuran; water; to Grignard reagent in THF is slowly added mercuric chloride in THF, mixt. is warmed to reflux for 1 h, colled to room temp., poured into aq. acetic acid contg. NaCl; solid is collected and dried, dissolving in CHCl3, filtn., concg. soln., recrystn. from EtOH;

DOI:10.1021/om00093a020

Reference yield:

cyclohexylsilatrane (31865-49-3) + mercury dichloride → cyclohexylmercury chloride (24371-94-6)

Guidance literature:

In [⁽²⁾H₆]acetone; byproducts: ClSi(OCH2CH2)3N; excess HgCl2, 50°C; not isolated, reaction followed by (1)H-NMR spectroscopy; Kinetics;

DOI:10.1016/0022-328X(85)80362-4

Reference yield:

→ cyclohexylmercury chloride (24371-94-6)

Guidance literature:

1) Bis-(trimethylsilyl)-quecksilber, Methoxycyclohexan, 2) ethanol. HCl;

upstream raw materials:

cyclohexylsilatrane

Downstream raw materials:

2-cyclohexyl-benzothiazole

3-cyclohexyl-1,2-diphenyl-1-propanone

diethyl (cyclohexylmethyl)propanedioate

diethyl 3-cyclohexyl-2-methylbutanedioate

Refernces

• 1、 Nies, J. Dirk,Bellama, Jon M.,Ben-Zvi, Nava. "DIRECT TRANSFER OF ALIPHATIC AND AROMATIC SUBSTITUENTS FROM ORGANOSILATRANES TO MERCURY(II) SPECIES". . p. 315 - 320. Retrieved 2007/10/02.