(R)-1-[(1S)-2-(DICYCLOHEXYLPHOSPHINO)FERROCENYL]ETHYLDICYCLOHEXYLPHOSPHINE

Base Information

• Chemical Name: (R)-1-[(1S)-2-(DICYCLOHEXYLPHOSPHINO)FERROCENYL]ETHYLDICYCLOHEXYLPHOSPHINE
• CAS No.: 167416-28-6
• Molecular Formula: C₃₆H₅₆FeP₂
• Molecular Weight: 606.635
• Hs Code.: 29310099
• Mol file: 167416-28-6.mol

Synonyms:Ferrocene,1-(dicyclohexylphosphino)-2-[1-(dicyclohexylphosphino)ethyl]-, [R-(R*,R*)]-;

Chemical Property of (R)-1-[(1S)-2-(DICYCLOHEXYLPHOSPHINO)FERROCENYL]ETHYLDICYCLOHEXYLPHOSPHINE

Chemical Property:

• PSA: 27.18000
• LogP: 11.13510
• Storage Temp.: under inert gas (nitrogen or Argon) at 2-8°C

Purity/Quality:

99%, ^*data from raw suppliers

(R)-(-)-1-[(S)-2-(Dicyclohexylphosphino)ferrocenyl]ethyldicyclohexylphosphine, min. 97% ^*data from reagent suppliers

Safty Information:

• Statements: 36/37/38
• Safety Statements: 24/25

MSDS Files:

SDS file from LookChem

Useful:

Technology Process of (R)-1-[(1S)-2-(DICYCLOHEXYLPHOSPHINO)FERROCENYL]ETHYLDICYCLOHEXYLPHOSPHINE

There total 1 articles about (R)-1-[(1S)-2-(DICYCLOHEXYLPHOSPHINO)FERROCENYL]ETHYLDICYCLOHEXYLPHOSPHINE which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 70.0%

1-(dicyclohexylphosphino)-2-[1-(dimethylamino)ethyl]ferrocene (1095658-52-8,171817-39-3,146960-92-1,159000-57-4) + acetic acid (64-19-7,77671-22-8) + dicyclohexylphosphane (829-84-5) → 1-(dicyclohexylphosphino)-2-[1-(dicyclohexylphosphino)ethyl]ferrocene (158923-07-0,167416-28-6,223390-61-2,246231-77-6,436101-26-7)

Guidance literature:

at 80 ℃; for 6h; Schlenk technique; Inert atmosphere;

DOI:10.1002/chem.201804150

Reference yield: 69.0%

1-(dicyclohexylphosphino)-2-[1-(dicyclohexylphosphino)ethyl]ferrocene (158923-07-0,167416-28-6,223390-61-2,246231-77-6,436101-26-7) + diacetonitriledichloridopalladium(II) (21264-32-4,13869-38-0,13869-42-6) + dichloromethane (75-09-2) → (C5H5)Fe(C5H3(CH(CH3)P(C6H11)2)P(C6H11)2)PtCl2*0.25CH2Cl2

Guidance literature:

In dichloromethane; under Ar atm. Pt complex and ligand in CH2Cl2 were stirred for 1 h; soln. was filtered and concd., Et2O was added, ppt. was filtered, washedwith Et2O and dried in vacuo; elem. anal.;

DOI:10.1016/j.jorganchem.2007.02.039

Reference yield: 20.0%

bis(benzonitrile)palladium(II) dichloride (15617-18-2,39958-10-6,14220-64-5) + 1-(dicyclohexylphosphino)-2-[1-(dicyclohexylphosphino)ethyl]ferrocene (158923-07-0,167416-28-6,223390-61-2,246231-77-6,436101-26-7) + dichloromethane (75-09-2) → (C5H5)Fe(C5H3(CH(CH3)P(C6H11)2)P(C6H11)2)PdCl2*0.25CH2Cl2

Guidance literature:

In dichloromethane; under Ar atm. Pd complex and ligand in CH2Cl2 were stirred for 24 h; soln. was filtered and evapd. in vacuo, residue was washed with Et2O anddried in vacuo; elem. anal.;

DOI:10.1016/j.jorganchem.2007.02.039

upstream raw materials:

1-(dicyclohexylphosphino)-2-[1-(dimethylamino)ethyl]ferrocene

acetic acid

dicyclohexylphosphane

Refernces