2-(Carbomethoxy)ethyltrichlorosilane

Base Information

• Chemical Name: 2-(Carbomethoxy)ethyltrichlorosilane
• CAS No.: 18147-81-4
• Deprecated CAS: 95061-83-9
• Molecular Formula: C4H7Cl3O2Si
• Molecular Weight: 221.543
• European Community (EC) Number: 242-036-1
• UNII: JJZ3D3R69Q
• DSSTox Substance ID: DTXSID0066321
• Nikkaji Number: J260.897I
• Wikidata: Q81992922
• Mol file: 18147-81-4.mol

Synonyms:2-(Carbomethoxy)ethyltrichlorosilane;18147-81-4;Methyl 3-(trichlorosilyl)propanoate;methyl 3-trichlorosilylpropanoate;Methyl 3-(trichlorosilyl)propionate;60839-24-9;Propanoic acid, 3-(trichlorosilyl)-, methyl ester;2-Carbomethoxyethyltrichlorosilane;EINECS 242-036-1;Propanoic acid, 2-(trichlorosilyl)-, methyl ester;JJZ3D3R69Q;SCHEMBL521654;DTXSID0066321;2(carbomethoxy)ethyltrichlorosilane;MFCD00018080;AKOS015911367;FS-5415;[2-(Methoxycarbonyl)ethyl]trichlorosilane

Chemical Property of 2-(Carbomethoxy)ethyltrichlorosilane

Chemical Property:

• Vapor Pressure: 0.387mmHg at 25°C
• Refractive Index: 1.455
• Boiling Point: 197 °C at 760 mmHg
• Flash Point: 72.9 °C
• PSA: 26.30000
• Density: 1.319 g/cm³
• LogP: 2.20480
• Hydrogen Bond Donor Count: 0
• Hydrogen Bond Acceptor Count: 2
• Rotatable Bond Count: 3
• Exact Mass: 219.928089
• Heavy Atom Count: 10
• Complexity: 122

Purity/Quality:

98% ^*data from raw suppliers

2-(CARBOMETHOXY)ETHYLTRICHLOROSILANE 95.00% ^*data from reagent suppliers

Safty Information:

• Statements: 10-34
• Safety Statements: 16-26-36/37/39

MSDS Files:

SDS file from LookChem

Useful:

• Canonical SMILES: COC(=O)CC[Si](Cl)(Cl)Cl

Technology Process of 2-(Carbomethoxy)ethyltrichlorosilane

There total 2 articles about 2-(Carbomethoxy)ethyltrichlorosilane which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

acrylic acid methyl ester (292638-85-8,9003-21-8,96-33-3) → methyl 3-(trichlorosilyl)propanoate (18147-81-4)

Guidance literature:

With copper(I) oxide; N,N,N,N,-tetramethylethylenediamine; trichlorosilane; at 5 ℃; for 80h; Product distribution; other silanes and acrylates; var. times, copper salts;

DOI:10.1016/0022-328X(93)80314-2

Reference yield:

trichlorosilane (10025-78-2) + acrylic acid methyl ester (292638-85-8,9003-21-8,96-33-3) + isopropyl alcohol (67-63-0,8013-70-5) → methyl 3-(trichlorosilyl)propanoate (18147-81-4)

Guidance literature:

Reference yield:

methyl magnesium iodide (917-64-6) + methyl 3-(trichlorosilyl)propanoate (18147-81-4) → methyl 3-(trimethylsilyl)propionate (18296-04-3)

Guidance literature:

upstream raw materials:

acrylic acid methyl ester

trichlorosilane

isopropyl alcohol

Downstream raw materials:

methyl 3-(trimethylsilyl)propionate

Refernces