Aurum iodatum

Base Information

• Chemical Name: Aurum iodatum
• CAS No.: 10294-31-2
• Molecular Formula: AuI
• Molecular Weight: 323.871
• UNII: T1UDV7ES1A
• Nikkaji Number: J95.925A
• Mol file: 10294-31-2.mol

Synonyms:gold(1+);iodide;Gold(I)iodide;Gold (I) Iodide;AUROUS IODIDE;AURUM IODATUM;AURUM IODATUM [HPUS];GOLD MONOIODIDE [MI]

Chemical Property of Aurum iodatum

Chemical Property:

• Vapor Pressure: 13.8mmHg at 25°C
• Melting Point: 120 °C (dec.)(lit.)
• Boiling Point: 127 °C at 760 mmHg
• PSA: 0.00000
• Density: 8.25 g/mL at 25 °C(lit.)
• LogP: 0.88320
• Storage Temp.: Keep in dark place,Inert atmosphere,Room temperature
• Sensitive.: Moisture Sensitive
• Water Solubility.: Insoluble in water. Soluble in alkali iodide, cyanide solutions. Decomposes in warm acids
• Hydrogen Bond Donor Count: 0
• Hydrogen Bond Acceptor Count: 1
• Rotatable Bond Count: 0
• Exact Mass: 323.87104
• Heavy Atom Count: 2
• Complexity: 0

Purity/Quality:

98%,99%, ^*data from raw suppliers

Gold(I) iodide, 99% (99.9+%-Au) ^*data from reagent suppliers

Safty Information:

• Pictogram(s): Xi
• Hazard Codes: Xi
• Statements: 36/37/38
• Safety Statements: 26-37/39

MSDS Files:

SDS file from LookChem

Useful:

• Canonical SMILES: [I-].[Au+]
• Uses: Gold(I) iodide is employed in the synthesis of chemicals.

Technology Process of Aurum iodatum

There total 18 articles about Aurum iodatum which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 88.0%

2-iodo-propane (75-30-9) + gold(III) chloride (21563-00-8) → gold(I) iodide (10294-31-2)

Guidance literature:

In dichloromethane; byproducts: I2, (CH3)2CHCl; treatment of a suspension of Au2Cl6 in CH2Cl2 with (CH3)2CHI; stirring for 24 h; N2-atmosphere, absence of light;; collection (filtration), drying (vac.); elem. anal.;

DOI:10.1039/DT9910003009

Reference yield:

gold(III) chloride (13453-07-1) → gold(I) iodide (10294-31-2) + Iodine monochloride (7790-99-0)

Guidance literature:

With iodine; In not given; ambient temp., slowly;

Reference yield:

gold(I) oxide (1303-57-7) → gold(I) iodide (10294-31-2) + gold (7440-57-5,457905-15-6)

Guidance literature:

With hydrogen iodide; In water; byproducts: iodine;

upstream raw materials:

gold

gold(I) oxide

iodine

potassium iodide

Downstream raw materials:

N,N'-diphenylformamidinato gold(I)

iodo[tris(2,4,6-trimethoxyphenyl)phosphine]gold(I)

Refernces

• 1、 Dell'Amico, Daniela Belli,Calderazzo, Fausto,Morvillo, Antonio,Pelizzi, Giancarlo,Robino, Pierluigi. "New Routes Towards Halogeno Complexes of Gold by Halide Exchange from . Crystal and Molecular Structure of Triphenylmethylium Tetrachloroaurate(III), ". . p. 3009 - 3016. Retrieved 2007/10/02.
• 2、 Dell'Amico, Daniela Belli,Calderazzo, Fausto,Robino, Pierluigi,Segre, Annalaura. "Halogenocarbonyl Complexes of Gold". . p. 3017 - 3020. Retrieved 2007/10/02.