4-Chloro-1,1,2-trifluoro-1-butene

Base Information

• Chemical Name: 4-Chloro-1,1,2-trifluoro-1-butene
• CAS No.: 378-81-4
• Molecular Formula: C₄ClF₇
• Molecular Weight: 216.486
• Hs Code.: 2903799090
• DSSTox Substance ID: DTXSID90958844
• Nikkaji Number: J2.614.273C
• Mol file: 378-81-4.mol

Synonyms:4-Chloro-1,1,2-trifluoro-1-butene;4-chloro-1,1,2-trifluorobut-1-ene;235106-11-3;MFCD00077488;1-Butene, 4-chloro-1,1,2-trifluoro-;4-chloro-1,1,2-trifluoro-but-1-ene;SCHEMBL5401871;DTXSID90958844;RRHUKZXPIZGLJG-UHFFFAOYSA-N;1,1,2-Trifluoro-4-chloro-1-butene;AKOS006228796;CS-0360328;FT-0676803;A823918

Chemical Property of 4-Chloro-1,1,2-trifluoro-1-butene

Chemical Property:

• Vapor Pressure: 70.4mmHg at 25°C
• Boiling Point: 87.9°Cat760mmHg
• Flash Point: 16.7°C
• PSA: 0.00000
• Density: 1.251g/cm³
• LogP: 2.69290
• XLogP3: 1.9
• Hydrogen Bond Donor Count: 0
• Hydrogen Bond Acceptor Count: 3
• Rotatable Bond Count: 2
• Exact Mass: 143.9953623
• Heavy Atom Count: 8
• Complexity: 95.5

Purity/Quality:

98% ^*data from raw suppliers

4-CHLOROHEPTAFLUOROBUT-1-ENE 95.00% ^*data from reagent suppliers

Safty Information:

• Hazard Codes: Xi,F
• Statements: 10
• Safety Statements: 16

MSDS Files:

Useful:

• Canonical SMILES: C(CCl)C(=C(F)F)F

Technology Process of 4-Chloro-1,1,2-trifluoro-1-butene

There total 3 articles about 4-Chloro-1,1,2-trifluoro-1-butene which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 3.8%

Allyl ether (557-40-4) + 1-chloro-4-iodo-1,1,2,2,3,3,4,4-octafluorobutane (5848-38-4) → 1-chloro-1,1,2,2,3,3,4,4-octafluorobutane (423-31-4) + 4-chloroheptafluoro-1-butene (378-81-4) + 3-(5-Chloro-2,2,3,3,4,4,5,5-octafluoro-pentyl)-4-iodomethyl-tetrahydro-furan (104729-99-9)

Guidance literature:

With magnesium; In tetrahydrofuran; for 5h; Heating;

DOI:10.1016/S0022-1139(00)81022-2

Reference yield:

1,2,4-trichloro-heptafluoro-butane (335-45-5) → 4-chloroheptafluoro-1-butene (378-81-4)

Guidance literature:

With hydrogenchloride; methanol; zinc;

Reference yield:

→ 4-chloroheptafluoro-1-butene (378-81-4)

Guidance literature:

5-Chlor-perfluorvaleriansaeure-Na-Salz, 340grad;

upstream raw materials:

1,2,4-trichloro-heptafluoro-butane

Allyl ether

1-chloro-4-iodo-1,1,2,2,3,3,4,4-octafluorobutane

Downstream raw materials:

trans-1-chloroheptafluoro-2-butene

Refernces