4-IODOBENZOPHENONE

Base Information

• Chemical Name: 4-IODOBENZOPHENONE
• CAS No.: 6136-66-9
• Molecular Formula: C13H9IO
• Molecular Weight: 308.118
• Hs Code.: 2914700090
• Mol file: 6136-66-9.mol

Synonyms:Benzophenone,4-iodo- (6CI,7CI,8CI);(4-Iodophenyl)phenylmethanone;4-Iodobenzophenone;p-Iodobenzophenone;(4-Iodophenyl)(phenyl)methanone;

Chemical Property of 4-IODOBENZOPHENONE

Chemical Property:

• Vapor Pressure: 1.45E-05mmHg at 25°C
• Melting Point: 97-99 °C
• Refractive Index: 1.647
• Boiling Point: 366.6 °C at 760 mmHg
• Flash Point: 175.5 °C
• PSA: 17.07000
• Density: 1.624 g/cm³
• LogP: 3.52220
• Storage Temp.: Keep in dark place,Sealed in dry,Room Temperature

Purity/Quality:

98%min ^*data from raw suppliers

4-Iodobenzophenone ^*data from reagent suppliers

Safty Information:

• Pictogram(s): Xi
• Hazard Codes: Xi
• Statements: 36/37/38
• Safety Statements: 26-36/37/39

MSDS Files:

SDS file from LookChem

Useful:

Technology Process of 4-IODOBENZOPHENONE

There total 37 articles about 4-IODOBENZOPHENONE which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 96.0%

4-iodobenzonitrile (3058-39-7) + phenylboronic acid (98-80-6) → 4-iodobenzophenone (6136-66-9)

Guidance literature:

With trifluorormethanesulfonic acid; palladium diacetate; 2-(3,5-dimethyl-1H-pyrazol-1-yl)pyridine; In water; at 60 ℃; for 6h;

DOI:10.1016/j.tetlet.2014.11.009

Reference yield: 96.0%

phenyl(4-((tetrafluoro-λ5-boranyl)diazenyl)phenyl)methanone → 4-iodobenzophenone (6136-66-9)

Guidance literature:

With trimethylsilyl iodide; methyl iodide; In N,N-dimethyl-formamide; for 1h; Ambient temperature;

DOI:10.1246/bcsj.62.89

Reference yield: 91.0%

4-iodobenzonitrile (3058-39-7) + benzenesufonyl hydrazide (80-17-1) → 4-iodobenzophenone (6136-66-9)

Guidance literature:

With 2,2'-biquinoline; water; palladium diacetate; In dimethyl sulfoxide; at 80 ℃; for 6h; under 760.051 Torr;

DOI:10.1021/acs.joc.8b00211

upstream raw materials:

4-iodobenzhydrol

4-dichloroiodanyl-benzophenone

iodobenzene

benzoyl chloride

Downstream raw materials:

1,2-bis-(4-iodo-phenyl)-1,2-diphenyl-ethane-1,2-diol

1,1-Diphenylmethanol

4-benzoylphenyl radical

1-benzyl-4-iodobenzene

Refernces

• 1、 Zhang, Yilan,Yue, Xiaoguang,Liang, Chenfeng,Zhao, Jianming,Yu, Wenbo,Zhang, Pengfei. "Photo-induced oxidative cleavage of C-C double bonds of olefins in water". supporting information. . Retrieved 2021/08/27.
• 2、 -. "Aryl aldiketone and synthesis method thereof". Paragraph 0030. . Retrieved 2021/09/26.