(Z)-POTASSIUMMETHANEDIAZOTATE

Base Information

• Chemical Name: (Z)-POTASSIUMMETHANEDIAZOTATE
• CAS No.: 3058-37-5
• Molecular Formula: CH4 N2 O . K
• Molecular Weight: 98.1459
• Hs Code.: 2924199090
• Mol file: 3058-37-5.mol

Synonyms:Methanediazohydroxide,potassium salt, (Z)- (8CI)

Chemical Property of (Z)-POTASSIUMMETHANEDIAZOTATE

Chemical Property:

• Vapor Pressure: 189mmHg at 25°C
• Boiling Point: 55.3°Cat760mmHg
• Flash Point: °C
• PSA: 47.78000
• Density: g/cm³
• LogP: 0.56620

Purity/Quality:

99% ^*data from raw suppliers

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

Technology Process of (Z)-POTASSIUMMETHANEDIAZOTATE

There total 3 articles about (Z)-POTASSIUMMETHANEDIAZOTATE which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

N-methyl-N-nitrosotoluene-p-sulfonamide (80-11-5) → (Z)-potassium methanediazotate (3058-37-5)

Guidance literature:

With potassium ethoxide; In diethyl ether; ethanol;

Reference yield:

methylhydrazine (60-34-4) → (E)-potassium methanediazotate (87039-32-5,98114-62-6,3058-37-5)

Guidance literature:

With ethyl nitrite; potassium ethoxide; In diethyl ether; ethanol; at 0 ℃; for 2h;

DOI:10.1016/S1383-5718(97)00180-0

Reference yield:

methanol (67-56-1) → (E)-potassium methanediazotate (87039-32-5,98114-62-6,3058-37-5)

Guidance literature:

With sodium hydroxide; sodium perchlorate; at 25 ℃; Equilibrium constant; var. buffers;

DOI:10.1021/ja00027a060

upstream raw materials:

methanol

methylhydrazine

N-methyl-N-nitrosotoluene-p-sulfonamide

Downstream raw materials:

methanol

2-diazo-1-(3-nitrophenyl)ethanone

N-methyl-N-nitrosotoluene-p-sulfonamide

ethyl N-methyl-N-nitrosocarbamate

Refernces

• 1、 Ukawa-Ishikawa, Satoko,Sawada, Atsuko,Kasuya, Keiko,Mochizuki, Masataka. "Mutagenicity of isomeric alkanediazotates, precursors for ultimate alkylating species of carcinogenic N-nitroso compounds". . p. 99 - 107. Retrieved 2007/10/03.