RUTHENIUM(III) NITROSYLCHLORIDE

Base Information

• Chemical Name: RUTHENIUM(III) NITROSYLCHLORIDE
• CAS No.: 18902-42-6
• Molecular Formula: Cl₃NORu
• Molecular Weight: 237.435
• Mol file: 18902-42-6.mol

Synonyms:RUTHENIUM NITROSYL CHLORIDE;RUTHENIUM NITROSO CHLORIDE;RUTHENIUM(III) NITROSYLCHLORIDE;trichloronitrosyl-rutheniu;Rutheniumnitrosylchloridemonohydrateredxtl;trichloronitrosylruthenium;RUTHENIUM (III) NITROSYL CHLORIDE MONOHYDRATE 99%;Ruthenium(III)nitrosylchloride,Ru42.1%min

Chemical Property of RUTHENIUM(III) NITROSYLCHLORIDE

Chemical Property:

• Melting Point: 180°C (dec.)
• Boiling Point: °Cat760mmHg
• Flash Point: °C
• PSA: 29.43000
• Density: g/cm³
• LogP: 2.28560
• Sensitive.: Hygroscopic
• Water Solubility.: Insoluble in water.

Purity/Quality:

98%,99%, ^*data from raw suppliers

Ruthenium(II) Nitrosyl Chloride Monohydrate >97.0%(T) ^*data from reagent suppliers

Safty Information:

• Pictogram(s): 3
• Hazard Codes: Xi:Irritant
• Statements: 34
• Safety Statements: 22-26-36/37/39

MSDS Files:

SDS file from LookChem

Useful:

• Uses: Ruthenium nitrosyl chloride is an important ruthenium compounds, which is used in synthesis of more complex ruthenium compounds.

Technology Process of RUTHENIUM(III) NITROSYLCHLORIDE

There total 12 articles about RUTHENIUM(III) NITROSYLCHLORIDE which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 95.0%

hydrogenchloride (7647-01-0,15364-23-5) + ruthenium trichloride (63767-78-2) + sodium nitrite (7632-00-0) → ruthenium(II)nitrosyl trichloride (18902-42-6)

Guidance literature:

In water; for 4h; Heating / reflux;

Reference yield: 95.0%

ruthenium trichloride hydrate (14898-67-0) + nitrogen(II) oxide (10102-43-9) → ruthenium(II)nitrosyl trichloride (18902-42-6)

Guidance literature:

In thionyl chloride; byproducts: SO2, HCl; RuCl3 suspended in SOCl2, vessel flushed with N2, pressurized with NO to2.76 bar, mixt. heated at 65°C for 12 h, cooled to room temp.; CCl4 added, filtered, elem. anal.;

DOI:10.1002/1099-0682(200007)2000:7<1609::AID-EJIC1609>3.0.CO;2-1

Reference yield: 84.0%

{Ru(NO)Cl3(water)2} → ruthenium(II)nitrosyl trichloride (18902-42-6)

Guidance literature:

With thionyl chloride; In thionyl chloride; byproducts: HCl, SO2; under N2 atm. Ru complex in SOCl2 was refluxed at 80°C for 2 days; ppt. was filtered and dried in vacuo;

DOI:10.1021/om800791n

upstream raw materials:

hydrogenchloride

ruthenium trichloride

sodium nitrite

ruthenium trichloride hydrate

Downstream raw materials:

ruthenium nitrosyl iodide

Refernces

• 1、 Cheng, Yong,Sun, Jia-Feng,Yang, Hong-Ling,Xu, Hui-Jun,Li, Yi-Zhi,Chen, Xue-Tai,Xue, Zi-Ling. "Syntheses, structures, and catalytic properties of ruthenium(II) nitrosyl complexes with pyridine-functionalized N-heterocyclic carbenes". . p. 819 - 823. Retrieved 2009.
• 2、 Tkachenko, V. Yu.,Dzhabieva,Shilov,Avdeeva,Dobrygin,Dzhabiev. "Synthesis and Crystal Structure of Binuclear Ruthenium Nitride Complex with Lithium Counter Cations as a Precatalyst of Water Oxidation Reaction in Artificial Photosynthesis". . p. 354 - 360. Retrieved 2021/03/23.
• 3、 -. "METHODS FOR PRODUCING NANOPARTICULATE METAL COMPLEXES AND ALTERING NANOPARTICLE MORPHOLOGY". Page/Page column 8; 9. . Retrieved 2010/11/25.