Perchloric acid, triethylsilyl ester

Base Information

• Chemical Name: Perchloric acid, triethylsilyl ester
• CAS No.: 18244-91-2
• Molecular Formula: C6H15ClO4Si
• Molecular Weight: 214.721
• Mol file: 18244-91-2.mol

Synonyms:Perchloric acid, triethylsilyl ester

Chemical Property of Perchloric acid, triethylsilyl ester

Chemical Property:

Purity/Quality:

99% ^*data from raw suppliers

Safty Information:

• Pictogram(s): 3
• Hazard Codes: 3

MSDS Files:

SDS file from LookChem

Useful:

Technology Process of Perchloric acid, triethylsilyl ester

There total 3 articles about Perchloric acid, triethylsilyl ester which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

triethylsilane (617-86-7) → Triethylsilanol (597-52-4) + triethylsilyl perchlorate (18244-91-2)

Guidance literature:

With oxygen; silver perchlorate; In benzene; at 25 ℃; Kinetics; Thermodynamic data; Rate constant; var. temperatures, other trialkyl silanes and trialkoxysilanes; effect of water, triethylamine, nitrobenzene, acrylonitrile, and oxygen atmosphere; ΔH(excit.), ΔS(excit.), ΔG(excit.);

Reference yield:

1-ethoxy-1-(triethylsiloxy)ethylene (73303-68-1) + p,p'-dimethoxytriphenylmethyl perchlorate → triethylsilyl perchlorate (18244-91-2) + 3,3-bis-(4-methoxy-phenyl)-3-phenyl-propionic acid ethyl ester

Guidance literature:

In acetonitrile; at 24.84 ℃; Kinetics;

DOI:10.1021/jo005733g

Reference yield:

tris(4-methoxyphenyl)methylium perchlorate + 1-ethoxy-1-(triethylsiloxy)ethylene (73303-68-1) → triethylsilyl perchlorate (18244-91-2) + 3,3,3-tris-(4-methoxy-phenyl)-propionic acid ethyl ester

Guidance literature:

In acetonitrile; at 24.84 ℃; Kinetics;

DOI:10.1021/jo005733g

upstream raw materials:

triethylsilane

1-ethoxy-1-(triethylsiloxy)ethylene

Downstream raw materials:

(S)-5-[(2S,5R,2'R,3'S,5'R)-5'-((2S,3S,5R,6R)-6-Benzyloxymethyl-6-methoxy-3,5-dimethyl-tetrahydro-pyran-2-yl)-2-ethyl-3'-methyl-octahydro-[2,2']bifuranyl-5-yl]-5-triethylsilanyloxy-hexan-2-one

Refernces

• 1、 Marciniec, Bogdan,Tran, Son. "OXIDATIVE CLEAVAGE OF Si-H BOND IN PRESENCE OF SILVER PERCHLORATE. PART II. KINETICS OF COMPETITIVE-CONSECUTIVE REACTION OF TRISUBSTITUTED SILANES IN BENZENE". . p. 827 - 835. Retrieved 2007/10/02.