AuClCH(P(C₆H₅)3)CO₂CH₃

Base Information

• Chemical Name: AuClCH(P(C₆H₅)3)CO₂CH₃
• CAS No.: 98255-90-4
• Molecular Formula: C₂₁H₁₉AuClO₂P
• Molecular Weight: 566.774
• Mol file: 98255-90-4.mol

Synonyms:AuClCH(P(C₆H₅)3)CO₂CH₃

Chemical Property of AuClCH(P(C₆H₅)3)CO₂CH₃

Chemical Property:

Purity/Quality:

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MSDS Files:

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Technology Process of AuClCH(P(C₆H₅)3)CO₂CH₃

There total 1 articles about AuClCH(P(C₆H₅)3)CO₂CH₃ which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 77.0%

(tetrahydrothiophene)gold(I) chloride (39929-21-0) + methyl (triphenylphosphoranylidene)acetate (21204-67-1,2605-67-6) → AuClCH(P(C6H5)3)CO2CH3 (98255-90-4)

Guidance literature:

In dichloromethane; to a soln. of Au-complex in CH2Cl2 was added solid ligand at room temp. with stirring;; after 30 min soln. was concd., Et2O was added, crystd. from CH2Cl2-Et2O; elem. anal.;;

DOI:10.1039/DT9850001163

Reference yield: 94.0%

AuClCH(P(C6H5)3)CO2CH3 (98255-90-4) → AuCl3CH(P(C6H5)3)CO2CH3 (98255-73-3)

Guidance literature:

With Cl₂; In tetrachloromethane; dichloromethane; to a soln. of Au-complex in CH2Cl2 was added a soln. of Cl2 in CCl4 at room temp. with stirring;; after 30 min soln. was concd., Et2O was added, ppt. was washed with Et2O; elem. anal.;;

DOI:10.1039/DT9850001163

Reference yield: 76.0%

AuClCH(P(C6H5)3)CO2CH3 (98255-90-4) + sodium perchlorate + methyl (triphenylphosphoranylidene)acetate (21204-67-1,2605-67-6) → {Au(CHP(C6H5)3COOCH3)2}(1+)*ClO4(1-)

Guidance literature:

In acetone; to a soln. of Au-complex in acetone was added solid ligand and NaClO4 at room temp. with stirring;; after 1 h solvent was evapd., residue was extd. with CH2Cl2, filtered off, concd., Et2O was added, recrystd. from CH2Cl2-Et2O; elem. anal.;;

DOI:10.1039/DT9850001163

upstream raw materials:

(tetrahydrothiophene)gold(I) chloride

methyl (triphenylphosphoranylidene)acetate

Downstream raw materials:

AuCl₃CH(P(C₆H₅)3)CO₂CH₃

Refernces