3-Bromo-9-phenylcarbazole

Base Information

• Chemical Name: 3-Bromo-9-phenylcarbazole
• CAS No.: 1153-85-1
• Molecular Formula: C18H12BrN
• Molecular Weight: 322.204
• Hs Code.: 2933990090
• Mol file: 1153-85-1.mol

Synonyms:3-Bromo-9-phenyl-9H-carbazole;3-Bromo-9-phenylcarbazole;Carbazole,3-bromo-9-phenyl- (8CI);

Chemical Property of 3-Bromo-9-phenylcarbazole

Chemical Property:

• Vapor Pressure: 1.05E-08mmHg at 25°C
• Melting Point: 98 °C
• Refractive Index: 1.672
• Boiling Point: 461.7 °C at 760 mmHg
• Flash Point: 233 °C
• PSA: 4.93000
• Density: 1.39 g/cm³
• LogP: 5.54620
• Storage Temp.: Sealed in dry,Room Temperature
• Water Solubility.: Slightly soluble in water.

Purity/Quality:

99%min ^*data from raw suppliers

3-Bromo-9-phenylcarbazole ^*data from reagent suppliers

Safty Information:

• Pictogram(s): Xn
• Hazard Codes: Xn

MSDS Files:

SDS file from LookChem

Useful:

• Uses: Used in manufacturing of OLED materials. Also used as intermediate for pharmaceutical.

Technology Process of 3-Bromo-9-phenylcarbazole

There total 24 articles about 3-Bromo-9-phenylcarbazole which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 99.0%

N-phenylcarbazole (1150-62-5) → 3-bromo-9-phenyl-9H-carbazole (1153-85-1)

Guidance literature:

With N-Bromosuccinimide; In ethyl acetate; toluene;

Reference yield: 96.0%

3-bromo-9H-carbazole (1592-95-6) + phenylhydrazine (100-63-0) → 3-bromo-9-phenyl-9H-carbazole (1153-85-1)

Guidance literature:

With 1,8-diazabicyclo[5.4.0]undec-7-ene; nickel dichloride; In acetonitrile; at 60 ℃; for 12h;

Reference yield: 93.0%

3-bromo-9H-carbazole (1592-95-6) + iodobenzene (591-50-4) → 3-bromo-9-phenyl-9H-carbazole (1153-85-1)

Guidance literature:

3-bromo-9H-carbazole; iodobenzene; In N,N-dimethyl-formamide; at 20 ℃; for 0.5h;

With copper(l) iodide; In N,N-dimethyl-formamide; at 100 ℃;

upstream raw materials:

N-phenylcarbazole

iodobenzene

9H-carbazole

tri-tert-butyl phosphine

Downstream raw materials:

N-phenyl-9H-carbazol-3-boronic acid

6-bromo-9,9'-diphenyl-9H,9'H-3,3'-bicarbazole

(9,9'-diphenyl-9H,9'H-[3,3'-biscarbazol]-6-yl)boronic acid

(N-phenyl)-N-(9-phenyl-9H-carbazole-3-yl)amine

Refernces

• 1、 Grisorio, Roberto,Dell'Aquila, Antonio,Romanazzi, Giuseppe,Suranna, Gian Paolo,Mastrorilli, Piero,Cosma, Pynalisa,Acierno, Domenico,Amendola, Eugenio,Ciccarella, Giuseppe,Nobile, Cosimo Francesco. "Novel bifluorene based conjugated systems: Synthesis and properties". . p. 627 - 634. Retrieved 2006.
• 2、 Yi, Rong-Huei,Lei, Ya-Chun,Tseng, Yeh-Hsiang,Lin, Yi-Fan,Cheng, Yen-Chia,Fang, Yu-Chuan,Ho, Cheng-Yung,Tsai, Wei-Wen,Chang, Chih-Hao,Lu, Chin-Wei. "Imidazolyl-Phenylcarbazole-Based Host Materials and Their Use for Co-host Designs in Phosphorescent OLEDs". . . Retrieved 2021/12/06.
• 3、 -. "Amine-based compound and organic light emitting diode comprising the same". Paragraph 0223; 0229-0230. . Retrieved 2021/03/16.