MESO-TETRAPHENYL-TETRABENZOPORPHINE

Base Information

• Chemical Name: MESO-TETRAPHENYL-TETRABENZOPORPHINE
• CAS No.: 119654-64-7
• Molecular Formula: C60H36N4Pd
• Molecular Weight: 919.393
• Mol file: 119654-64-7.mol

Synonyms:Palladium,[6,13,20,27-tetraphenyl-29H,31H-tetrabenzo[b,g,l,q]porphinato(2-)-N29,N30,N31,N32]-,(SP-4-1)-;29H,31H-Tetrabenzo[b,g,l,q]porphine, 6,13,20,27-tetraphenyl-,palladium complex;29H,31H-Tetrabenzo[b,g,l,q]porphine, palladium deriv.;meso-Tetraphenyl-tetrabenzoporphine;

Chemical Property of MESO-TETRAPHENYL-TETRABENZOPORPHINE

Chemical Property:

• PSA: 50.50000
• LogP: 10.32900
• Storage Temp.: 2-8°C

Purity/Quality:

98%Min ^*data from raw suppliers

meso-Tetraphenyl-tetrabenzoporphinePalladiumComplex ^*data from reagent suppliers

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

• Description: Pt(II) meso-Tetraphenyl Tetrabenzoporphine is a synthetic porphyrin based product with photophysical properties related to energy up-conversion. Phosphorescent probe for measuring oxygen in very low concentrations. Luminescent marker for oxygen and pH in biomedical imaging. Used as agent for PDT, optical limiters and other types of nonlinear optical materials.
• Uses: meso-Tetraphenyl-tetrabenzoporphine Palladium Complex is a phosphorescent probe.

Technology Process of MESO-TETRAPHENYL-TETRABENZOPORPHINE

There total 8 articles about MESO-TETRAPHENYL-TETRABENZOPORPHINE which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 80.0%

cadmium(II) 5,10,15,20-tetraphenyl tetrabenzoporphyrinate (80529-83-5) + palladium dichloride → palladium(II) 5,10,15,20-tetraphenyltetrabenzoporphyrinate (119654-64-7)

Guidance literature:

In N,N-dimethyl-formamide; for 0.00833333h; Reflux;

DOI:10.1134/S0036023618050200

Reference yield: 64.0%

palladium diacetate (3375-31-3) + meso-tetraphenyltetrabenzoporphyrin (80528-89-8) → palladium(II) 5,10,15,20-tetraphenyltetrabenzoporphyrinate (119654-64-7)

Guidance literature:

In dichloromethane; N,N-dimethyl-formamide; at 150 ℃; for 1h;

DOI:10.1039/c5cc04325e

Reference yield: 25.0%

meso-tetraphenyltetrabenzoporphyrin (80528-89-8) + palladium dichloride → palladium(II) 5,10,15,20-tetraphenyltetrabenzoporphyrinate (119654-64-7)

Guidance literature:

In N,N-dimethyl-formamide; for 0.0833333h; Reflux;

DOI:10.1134/S0036023618050200

upstream raw materials:

sodium phenylacetate

phenylacetic acid

palladium diacetate

meso-tetraphenyltetrabenzoporphyrin

Downstream raw materials:

(22,23,72,73,122,123,172,173-octabromo-5,10,15,20-tetraphenyltetrabenzoporphyrinato)palladium(II)

Refernces

• 1、 Tao, Renjie,Zhao, Jianzhang,Zhong, Fangfang,Zhang, Caishun,Yang, Wenbo,Xu, Kejing. "H2O2-activated triplet-triplet annihilation upconversion via modulation of the fluorescence quantum yields of the triplet acceptor and the triplet-triplet-energy-transfer efficiency". . p. 12403 - 12406. Retrieved 2015/08/03.