1-(p-chlorophenylthio)-1-nitrocyclobutane

Base Information

• Chemical Name: 1-(p-chlorophenylthio)-1-nitrocyclobutane
• CAS No.: 1402833-01-5
• Molecular Formula: C₁₀H₁₀ClNO₂S
• Molecular Weight: 243.714
• Mol file: 1402833-01-5.mol

Synonyms:1-(p-chlorophenylthio)-1-nitrocyclobutane

Chemical Property of 1-(p-chlorophenylthio)-1-nitrocyclobutane

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
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MSDS Files:

Useful:

Technology Process of 1-(p-chlorophenylthio)-1-nitrocyclobutane

There total 2 articles about 1-(p-chlorophenylthio)-1-nitrocyclobutane which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 70.0%

4,4'-dichlorodiphenyl disulfide (1142-19-4) + nitrocyclobutane (2625-41-4) → 1-(p-chlorophenylthio)-1-nitrocyclobutane (1402833-01-5)

Guidance literature:

With hydridotetakis(triphenylphosphine)rhodium(I); 1,2-bis-(diphenylphosphino)ethane; In N,N-dimethyl acetamide; at 20 ℃; for 3h;

DOI:10.1016/j.tetlet.2012.07.132

Reference yield:

1-(p-chlorophenylthio)-1-nitrohexane (1402832-93-2) → 1-(p-chlorophenylthio)-1-nitrocyclobutane (1402833-01-5)

Guidance literature:

Multi-step reaction with 2 steps

1: hydridotetakis(triphenylphosphine)rhodium(I); 1,2-bis-(diphenylphosphino)ethane / N,N-dimethyl acetamide / 3 h / 20 °C / Inert atmosphere

2: hydridotetakis(triphenylphosphine)rhodium(I); 1,2-bis-(diphenylphosphino)ethane / N,N-dimethyl acetamide / 3 h / 20 °C

With hydridotetakis(triphenylphosphine)rhodium(I); 1,2-bis-(diphenylphosphino)ethane; In N,N-dimethyl acetamide;

DOI:10.1016/j.tetlet.2012.07.132

upstream raw materials:

4,4'-dichlorodiphenyl disulfide

nitrocyclobutane

1-(p-chlorophenylthio)-1-nitrohexane

Refernces