Technology Process of p-methoxymethylbenzylmercury chloride
There total 1 articles about p-methoxymethylbenzylmercury chloride which
guide to synthetic route it.
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synthetic route:
- Guidance literature:
-
In
diethyl ether;
byproducts: HCl; to HgCl2 soln. mixt. of 1-methylene-6-methoxymethyl-2,4-cyclohexadiene,1-methylene-4-methoxymethyl-2,5-cyclohexadiene added dropwise with stirring (30 min, 20°C); solvent distd.; abs. CH3OH added; let stand (12 h, -50°C); total yield: 85%; decanted; filtered; washed (pentane); dried in vacuo; recrystd. (hexane); soln. in CH2Cl2 chromd. (silica gel, mixt. of CHCl3-ethyl acetate); first fraction recrystd. (hexane); second fraction recrystd.(mixt. of hexane-benzene); elem. anal.; UV; NMR;
DOI:10.1007/BF01168279
- Guidance literature:
-
With
hydrogenchloride;
In
1,4-dioxane;
byproducts: p-methylbenzyl methyl ether; to soln. of CH3OCH2(C6H4)CH2HgCl added soln. of HCl; kept in sealed ampul (6 h; 100°C); solvent vac.-distd.; crystals (HgCl2) filtered;
DOI:10.1007/BF01168279
