C₅₂H₇₅NO₂₁S

Base Information

• Chemical Name: C₅₂H₇₅NO₂₁S
• CAS No.: 1642888-07-0
• Molecular Formula: C₅₂H₇₅NO₂₁S
• Molecular Weight: 1082.23
• Mol file: 1642888-07-0.mol

Synonyms:C₅₂H₇₅NO₂₁S

Chemical Property of C₅₂H₇₅NO₂₁S

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of C₅₂H₇₅NO₂₁S

There total 6 articles about C₅₂H₇₅NO₂₁S which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 51.0%

1,3-propanesultone (1120-71-4) + C50H71NO18 (1642888-06-9) → C52H75NO21S (1642888-07-0)

Guidance literature:

With 2,6-di-tert-butyl-pyridine; 3-butyl-1-methyl-1H-imidazol-3-ium hexafluorophosphate; at 150 ℃; for 24h;

DOI:10.1039/c4ra02516d

Reference yield:

C53H77NO21S → C52H75NO21S (1642888-07-0)

Guidance literature:

With hydrogenchloride; In water; for 2h; Reflux; Inert atmosphere;

Reference yield:

1,3-dimethyl glycerol ether (623-69-8) → C52H75NO21S (1642888-07-0)

Guidance literature:

Multi-step reaction with 3 steps

1: potassium hydroxide / 16 h / 80 °C / Inert atmosphere

2: triphenylphosphine; triethylamine; di-isopropyl azodicarboxylate / tetrahydrofuran / 3.1 h / 0 - 20 °C / Inert atmosphere

3: 3-butyl-1-methyl-1H-imidazol-3-ium hexafluorophosphate; 2,6-di-tert-butyl-pyridine / 24 h / 150 °C

With 2,6-di-tert-butyl-pyridine; di-isopropyl azodicarboxylate; triethylamine; triphenylphosphine; 3-butyl-1-methyl-1H-imidazol-3-ium hexafluorophosphate; potassium hydroxide; In tetrahydrofuran;

DOI:10.1039/c4ra02516d

upstream raw materials:

1,3-propanesultone

C₅₀H₇₁NO₁₈

1,3-dimethyl glycerol ether

C₁₃H₂₈O₇

Downstream raw materials:

C₅₈H₈₉N₃O₂₂S

Refernces

• 1、 Natrajan, Anand,Wen, David. "Effect of branching in remote substituents on light emission and stability of chemiluminescent acridinium esters". . p. 21852 - 21863. Retrieved 2014/06/23.