isopropryl mercuric bromide

Base Information

• Chemical Name: isopropryl mercuric bromide
• CAS No.: 18819-83-5
• Molecular Formula: C3H7 Br Hg
• Molecular Weight: 323.583
• Hs Code.: 2931900090
• Mol file: 18819-83-5.mol

Synonyms:Isopropylmercurybromide (6CI); Mercury, bromoisopropyl- (8CI); Bromoisopropylmercury;Isopropylmercuric bromide

Chemical Property of isopropryl mercuric bromide

Chemical Property:

• PSA: 0.00000
• LogP: 2.20710

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

Technology Process of isopropryl mercuric bromide

There total 3 articles about isopropryl mercuric bromide which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 77.0%

{(η5-C5Me5)Os(CO)2i-Pr} (116669-98-8) + mercury dibromide → {(η5-C5Me5)Os(CO)2Br} (81554-89-4) + isopropylmercury (1+); bromide (18819-83-5) + isopropyl bromide (75-26-3)

Guidance literature:

In dichloromethane-d2; (N2); electrophilic cleavage reaction by addn. of HgBr2 to a soln. of Cp*Os(CO)2i-Pr in CD2Cl2;; not isolated, detected by NMR;;

Reference yield: 73.0%

{(η5-C5Me5)Os(CO)(PMe2Ph)i-Pr} (116670-01-0) + mercury dibromide → {(η5-C5Me5)Os(CO)(PMe2Ph)Br} (107087-80-9) + isopropylmercury (1+); bromide (18819-83-5)

Guidance literature:

In dichloromethane-d2; (N2); electrophilic cleavage reaction by addn. of HgBr2 to a soln. of Cp*Os(CO)(PMe2Ph)i-Pr in CD2Cl2;; not isolated, detected by NMR;;

Reference yield:

bromo-triphenyl-methane (596-43-0) + diisopropylmercury (1071-39-2) → triphenylmethyl alcohol (76-84-6) + triphenylmethane (519-73-3) + isopropylmercury (1+); bromide (18819-83-5) + isopropyl triphenylmethyl peroxide (78504-77-5)

Guidance literature:

With air; In 1,2-dichloro-ethane; Yield given. Yields of byproduct given. Title compound not separated from byproducts;

upstream raw materials:

bromo-triphenyl-methane

diisopropylmercury

{(η5-C5Me5)Os(CO)2i-Pr}

{(η5-C5Me5)Os(CO)(PMe2Ph)i-Pr}

Refernces

• 1、 Uglova, E. V.,Makhaev, V. D.,Reutov, O. A.. "OXIDATIVE TRITYLDEMERCURATION OF ORGANOMERCURY COMPOUNDS". . p. 1386 - 1389. Retrieved 2007/10/02.