Zirconium(IV) ethoxide

Base Information

• Chemical Name: Zirconium(IV) ethoxide
• CAS No.: 18267-08-8
• Molecular Formula: C2H6 O . 1/4 Zr
• Molecular Weight: 271.468
• Hs Code.: 29319090
• DSSTox Substance ID: DTXSID20431998
• Nikkaji Number: J877.513C
• Mol file: 18267-08-8.mol

Synonyms:Zirconium(IV) ethoxide;18267-08-8;Tetraethoxyzirconium(IV);DTXSID20431998;AKOS025294769;FT-0751098

Chemical Property of Zirconium(IV) ethoxide

Chemical Property:

• Vapor Pressure: 82.8mmHg at 25°C
• Melting Point: 200 °C
• Boiling Point: 235 °C5 mm Hg(lit.)
• Flash Point: 235°C/5mm
• PSA: 36.92000
• LogP: 1.94880
• Sensitive.: Moisture Sensitive
• Water Solubility.: Reacts with water.
• Hydrogen Bond Donor Count: 0
• Hydrogen Bond Acceptor Count: 4
• Rotatable Bond Count: 0
• Exact Mass: 270.040858
• Heavy Atom Count: 13
• Complexity: 2.8

Purity/Quality:

98%,99%, ^*data from raw suppliers

Zirconium(IV) ethoxide, 99+% ^*data from reagent suppliers

Safty Information:

• Hazard Codes: F,Xi
• Statements: 11-36/37/38
• Safety Statements: 26

MSDS Files:

SDS file from LookChem

Useful:

• Canonical SMILES: CC[O-].CC[O-].CC[O-].CC[O-].[Zr+4]
• Uses: Zirconium(IV) ethoxide is used as precursor for the synthesis of olefin-functionalized zirconium-containing monomers.

Technology Process of Zirconium(IV) ethoxide

There total 2 articles about Zirconium(IV) ethoxide which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

→ zirconium ethoxide (18267-08-8)

Guidance literature:

Herstellung;

DOI:10.1039/jr9510000280

Reference yield:

zirconium (7440-67-7) + ethanol (64-17-5) → zirconium ethoxide (18267-08-8)

Guidance literature:

Electrochem. Process; Zr-anode, Pt- or steel-cathode, Bu4NBr or LiCl as conductive additive (0.05-0.1 N), 110 V, 0.05 A/cm**2, refluxing electrolyte, 10-20 h; alcohol evapn., extraction (hexane), drying; elem. anal.;

DOI:10.1007/BF00698513

Reference yield:

water (7732-18-5) + zirconium ethoxide (18267-08-8) → zirconium(IV) oxide (7440-67-7)

Guidance literature:

With acetic acid; In ethanol; byproducts: C2H5OH; soln. of alkoxide in alc. combined with soln. of water in the same alc.(CH3COOH for dissolution), dried at 100°C, calcined at 500°C, hot pressed (4000 psi); X-ray diffraction;

DOI:10.1007/BF01117398

upstream raw materials:

zirconium

ethanol

Downstream raw materials:

zirconium(IV) oxide

Refernces