(DIISOPROPYLAMINO)TRIMETHYLSILANE

Base Information

• Chemical Name: (DIISOPROPYLAMINO)TRIMETHYLSILANE
• CAS No.: 17425-88-6
• Molecular Formula: C9H23NSi
• Molecular Weight: 173.374
• Hs Code.: 2931900090
• Mol file: 17425-88-6.mol

Synonyms:Silylamine,N,N-diisopropyl-1,1,1-trimethyl- (7CI,8CI);(Diisopropylamino)trimethylsilane;N,N-Diisopropyl(trimethylsilyl)amine;N-(Trimethylsilyl)diisopropylamine;Trimethylsilyldiisopropylamine;

Chemical Property of (DIISOPROPYLAMINO)TRIMETHYLSILANE

Chemical Property:

• Appearance/Colour: Clear colorless liquid
• Vapor Pressure: 3.63mmHg at 25°C
• Refractive Index: 1.4232
• Boiling Point: 157 °C at 760 mmHg
• Flash Point: 28.3 °C
• PSA: 3.24000
• Density: 0.785g/cm³
• LogP: 2.94010

Purity/Quality:

98%,99%, ^*data from raw suppliers

Safty Information:

• Pictogram(s): R10-36/37/38:
• Hazard Codes: C
• Statements: 10-36/37/38-34
• Safety Statements: 16-26-36/37/39-45

MSDS Files:

SDS file from LookChem

Useful:

Technology Process of (DIISOPROPYLAMINO)TRIMETHYLSILANE

There total 6 articles about (DIISOPROPYLAMINO)TRIMETHYLSILANE which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 7.0%

chloro-trimethyl-silane (75-77-4) + diisopropylamine (108-18-9) → N,N-diisopropyl-1,1,1-trimethylsilylamine (17425-88-6)

Guidance literature:

diisopropylamine; With n-butyllithium; In diethyl ether; hexane; at -20 - 20 ℃; Inert atmosphere;

chloro-trimethyl-silane; In diethyl ether; hexane; at -78 - 20 ℃; for 18.5h; Inert atmosphere;

DOI:10.1039/b923196j

Reference yield:

diisopropylamine (108-18-9) + methyl iodide (74-88-4) → N,N-diisopropyl-1,1,1-trimethylsilylamine (17425-88-6)

Guidance literature:

With chloro-trimethyl-silane; iodine; magnesium;

Reference yield:

chloro-trimethyl-silane (75-77-4) + lithium diisopropyl amide (4111-54-0) → N,N-diisopropyl-1,1,1-trimethylsilylamine (17425-88-6)

Guidance literature:

upstream raw materials:

chloro-trimethyl-silane

isopropylamine

propionaldehyde oxime

lithium diisopropyl amide

Downstream raw materials:

chloro-diisopropyl-amine

N,N-Diisopropyl-Se-phenyl-selenohydroxylamine

2-cyanoethyl-N,N-(diisopropylamino)chlorophosphine

vinyl N,N-diisopropylcarbamate

Refernces

• 1、 Buerger,Neese. "". . p. 243,250. Retrieved 1969.
• 2、 Schulz, Felix,Sumerin, Victor,Leskelae, Markku,Repo, Timo,Rieger, Bernhard. "Frustrated Lewis pairs: Reactivities of TMS protected amines and phosphines in the presence of B(C6F5)3". supporting information; experimental part. p. 1920 - 1922. Retrieved 2010/05/15.
• 3、 Hassner, Alfred,Naeumann, Fritz. "Alkylation and Aldol Reactions of Aldoxime Anions". . p. 1823 - 1826. Retrieved 2007/10/02.