ALLYL PHENYL CARBONATE 97

Base Information

• Chemical Name: ALLYL PHENYL CARBONATE 97
• CAS No.: 16308-68-2
• Molecular Formula: C10H10 O3
• Molecular Weight: 178.188
• Hs Code.: 2920909090
• Mol file: 16308-68-2.mol

Synonyms:Carbonicacid, allyl phenyl ester (8CI); Carbonic acid, phenyl 2-propenyl ester (9CI);Allyl phenyl carbonate

Chemical Property of ALLYL PHENYL CARBONATE 97

Chemical Property:

• Vapor Pressure: 0.0195mmHg at 25°C
• Refractive Index: n20/D 1.4990(lit.)
• Boiling Point: 67-70 °C0.3 mm Hg(lit.)
• Flash Point: >230 °F
• PSA: 35.53000
• Density: 1.096 g/mL at 25 °C(lit.)
• LogP: 2.38800
• Storage Temp.: under inert gas (nitrogen or Argon) at 2-8°C

Purity/Quality:

98% ^*data from raw suppliers

Allyl phenyl carbonate ^*data from reagent suppliers

Safty Information:

• Hazard Codes: Xn
• Statements: 22-36-43
• Safety Statements: 26-36/37/39

MSDS Files:

SDS file from LookChem

Useful:

• Uses: Allyl phenyl carbonate can react with (2-alkynyl)phenylisocyanate, catalyzed P(0)/Cu(I) system to give the corresponding indole.

Technology Process of ALLYL PHENYL CARBONATE 97

There total 5 articles about ALLYL PHENYL CARBONATE 97 which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 100.0%

allyl alcohol (107-18-6) + phenyl chloroformate (1885-14-9) → allyl phenyl carbonate (16308-68-2)

Guidance literature:

With pyridine; In dichloromethane; at 23 ℃; for 4h; Inert atmosphere;

DOI:10.1002/ejoc.200800141

Reference yield: 97.0%

→ allyl phenyl carbonate (16308-68-2)

Guidance literature:

Reference yield: 88.0%

Allyl chloroformate (2937-50-0) + phenol (108-95-2,27073-41-2) → allyl phenyl carbonate (16308-68-2)

Guidance literature:

With pyridine; at 0 - 20 ℃;

DOI:10.1021/ol202270g

upstream raw materials:

bis(phenyl) carbonate

allyl alcohol

phenyl chloroformate

bis(trichloromethyl) carbonate

Downstream raw materials:

allyl dibutylcarbamate

phenol

propene

allyl phenyl ether

Refernces

• 1、 Trivedi, Rushi,Tunge, Jon A.. "Regioselective iron-catalyzed decarboxylative allylic etherification". supporting information; experimental part. p. 5650 - 5652. Retrieved 2010/02/28.
• 2、 Breen, Gary F.. "Enzymatic resolution of a secondary amine using novel acylating reagents". . p. 1427 - 1430. Retrieved 2007/10/03.