6,11-bis[(4-methylphenyl)sulfonyl]-1-ferrocenylsulfonyl-1,6,11-triazaciclopentadeca-3,8,13-triyne

Base Information

• Chemical Name: 6,11-bis[(4-methylphenyl)sulfonyl]-1-ferrocenylsulfonyl-1,6,11-triazaciclopentadeca-3,8,13-triyne
• CAS No.: 700868-23-1
• Molecular Formula: C₃₆H₃₅FeN₃O₆S₃
• Molecular Weight: 757.735
• Mol file: 700868-23-1.mol

Synonyms:6,11-bis[(4-methylphenyl)sulfonyl]-1-ferrocenylsulfonyl-1,6,11-triazaciclopentadeca-3,8,13-triyne

Chemical Property of 6,11-bis[(4-methylphenyl)sulfonyl]-1-ferrocenylsulfonyl-1,6,11-triazaciclopentadeca-3,8,13-triyne

Chemical Property:

Purity/Quality:

Safty Information:

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MSDS Files:

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Technology Process of 6,11-bis[(4-methylphenyl)sulfonyl]-1-ferrocenylsulfonyl-1,6,11-triazaciclopentadeca-3,8,13-triyne

There total 2 articles about 6,11-bis[(4-methylphenyl)sulfonyl]-1-ferrocenylsulfonyl-1,6,11-triazaciclopentadeca-3,8,13-triyne which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 75.0%

1,11-bis[(4-methylphenyl)sulfonyl]-6-ferrocenylsulfonyl-1,6,11-triazaundeca-3,8-diyne (700868-22-0) + 1,4-dibromobut-2-yne (2219-66-1) → 6,11-bis[(4-methylphenyl)sulfonyl]-1-ferrocenylsulfonyl-1,6,11-triazaciclopentadeca-3,8,13-triyne (700868-23-1)

Guidance literature:

With K₂CO₃; In acetonitrile; stirred mixt. Fe complex, dibromide (1.16 equiv.) and K2CO3 in CH3CN wasrefluxed for 5.5 h; filtered; filtrate evapd.; residue chromd. (silica gel, hexane/EtOAc, 9/1 to 6/4); elem. anal.;

DOI:10.1021/om034384o

Reference yield: 53.0%

1,11-bis[(4-methylphenyl)sulfonyl]-6-ferrocenylsulfonyl-1,6,11-triazaundeca-3,8-diyne (700868-22-0) + 1,4-bis(methanesulfonyloxy)-2-butyne (2917-96-6) → 6,11-bis[(4-methylphenyl)sulfonyl]-1-ferrocenylsulfonyl-1,6,11-triazaciclopentadeca-3,8,13-triyne (700868-23-1)

Guidance literature:

With K₂CO₃; In acetonitrile; stirred mixt. Fe complex, bismethanesulfonate (1.16 equiv.) and K2CO3 inCH3CN was refluxed for 5.5 h; filtered; filtrate evapd.; residue chromd. (silica gel, hexane/EtOAc, 9/1 to 6/4);

DOI:10.1021/om034384o

upstream raw materials:

1,11-bis[(4-methylphenyl)sulfonyl]-6-ferrocenylsulfonyl-1,6,11-triazaundeca-3,8-diyne

1,4-dibromobut-2-yne

1,4-bis(methanesulfonyloxy)-2-butyne

Refernces