AsBr₄⁽¹⁺⁾*AsF₆^(1-)={AsBr₄}{AsF₆}

Base Information

• Chemical Name: AsBr₄⁽¹⁺⁾*AsF₆^(1-)={AsBr₄}{AsF₆}
• CAS No.: 119484-31-0
• Molecular Formula: AsBr₄*AsF₆
• Molecular Weight: 583.45
• Mol file: 119484-31-0.mol

Synonyms:AsBr₄⁽¹⁺⁾*AsF₆^(1-)={AsBr₄}{AsF₆}

Chemical Property of AsBr₄⁽¹⁺⁾*AsF₆^(1-)={AsBr₄}{AsF₆}

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of AsBr₄⁽¹⁺⁾*AsF₆^(1-)={AsBr₄}{AsF₆}

There total 2 articles about AsBr₄⁽¹⁺⁾*AsF₆^(1-)={AsBr₄}{AsF₆} which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 60.0%

arsenic pentafluoride (7784-36-3) + arsenic(III) bromide (7784-33-0) → AsBr4(1+)*AsF6(1-)={AsBr4}{AsF6} (119484-31-0) + arsenic(III) fluoride (7784-35-2)

Guidance literature:

With bromine; Condensing of AsF5 onto Br2 and AsBr3 at -196°C, warming to -5°C until a clear soln. is formed (1 min), cooling (-196°C), repeating of process in excess of 10 times.; Evapn. of volatiles in vac (-5°C, 10 min).;

DOI:10.1039/DT9900003815

Reference yield:

arsenic pentafluoride (7784-36-3) + bromine (7726-95-6) + arsenic(III) bromide (7784-33-0) → AsBr4(1+)*AsF6(1-)={AsBr4}{AsF6} (119484-31-0) + arsenic(III) fluoride (7784-35-2)

Guidance literature:

AsF5 condensed at -196°C onto a mixture of Br2 and AsBr3, warmed to -5°C, recooled to -196°C (repeated for more than 10 times); AsF3 removed at -5°C under dynamic vac.;

DOI:10.1039/C39880001426

Reference yield:

AsBr4(1+)*AsF6(1-)={AsBr4}{AsF6} (119484-31-0) → arsenic(III) fluoride (7784-35-2)

Guidance literature:

byproducts: Br2; Decompn. at room temp.; Raman.;

DOI:10.1039/DT9900003815

upstream raw materials:

arsenic pentafluoride

bromine

arsenic(III) bromide

Downstream raw materials:

bromine

arsenic(III) fluoride

Refernces

• 1、 Klapoetke, Thomas,Passmore, Jack,Awere, Edward G.. "The Preparation and Characterisation by Raman Spectroscopy of AsBr4+AsF6- containing the Tetrabromoarsenic (V) Cation". . p. 1426 - 1427. Retrieved 1988.