PENT-4-ENYLAMINE HYDROCHLORIDE

Base Information

• Chemical Name: PENT-4-ENYLAMINE HYDROCHLORIDE
• CAS No.: 22537-07-1
• Molecular Formula: C5H11N
• Molecular Weight: 85.149
• Hs Code.: 2921199090
• Mol file: 22537-07-1.mol

Synonyms:4-Pentenylamine(6CI,7CI,8CI);1-Amino-4-pentene;4-Penten-1-ylamine;4-Pentenamine;5-Aminopent-1-ene;

Chemical Property of PENT-4-ENYLAMINE HYDROCHLORIDE

Chemical Property:

• Vapor Pressure: 44.1mmHg at 25°C
• Refractive Index: 1.428
• Boiling Point: 96.1 °C at 760 mmHg
• PKA: 10.32±0.10(Predicted)
• Flash Point: 4.4 °C
• PSA: 26.02000
• Density: 0.775 g/cm³
• LogP: 1.61160

Purity/Quality:

99% ^*data from raw suppliers

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

• Uses: In the presence of sugars, lysine, similarly to asparagine and phenylalanine, can undergo carbonyl-assisted decarboxylative deamination reaction to generate pent-4-en-1-amine, the counterpart of acryl amide.

Technology Process of PENT-4-ENYLAMINE HYDROCHLORIDE

There total 27 articles about PENT-4-ENYLAMINE HYDROCHLORIDE which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 100.0%

4-pentenyl mesylate (64818-35-5) → 4-pentenyl-1-amine (22537-07-1)

Guidance literature:

With ammonia; In methanol; water; at 20 ℃; for 18h;

DOI:10.1021/ol4029513

Reference yield: 88.0%

2-(pent-4-enyl)-isoindoline-1,3-dione (7736-25-6) → 4-pentenyl-1-amine (22537-07-1)

Guidance literature:

With hydrazine hydrate; In ethanol; at 50 ℃; for 1h; Reflux;

Reference yield: 81.0%

4-Pentenenitrile (592-51-8) → 4-pentenyl-1-amine (22537-07-1)

Guidance literature:

With lithium aluminium tetrahydride; In diethyl ether; Heating;

DOI:10.1021/ol050294z

upstream raw materials:

2-(pent-4-enyl)-isoindoline-1,3-dione

4-Pentenenitrile

5-chloropent-1-ene

1-amino-pent-4-yne

Downstream raw materials:

4-pentenyl isothiocyanate

2-methyl-1-pyrrolidine

N-(pent-4-en-1yl)benzamide

((E)-Buta-1,3-dienyl)-pent-4-enyl-carbamic acid phenyl ester

Refernces

• 1、 Claridge,D.V.,Venanzi,L.M.. "-". . p. 3419 - 3423. Retrieved 1964.
• 2、 Escolano, Marcos,Torres Fernández, Javier,Rabasa-Alca?iz, Fernando,Sánchez-Roselló, María,Del Pozo, Carlos. "Enantioselective Synthesis of Pyrrolizidinone Scaffolds through Multiple-Relay Catalysis". . p. 9433 - 9438. Retrieved 2020.
• 3、 Chen, Chaohuang,Chen, Pinhong,Hou, Chuanqi,Liu, Guosheng. "Palladium(II)-Catalyzed Aminotrifluoromethoxylation of Alkenes: Mechanistic Insight into the Effect of N-Protecting Groups". supporting information. p. 346 - 350. Retrieved 2020/05/25.