TRI-N-BUTYL SILYL METHACRYLATE

Base Information

• Chemical Name: TRI-N-BUTYL SILYL METHACRYLATE
• CAS No.: 22414-62-6
• Molecular Formula: C16H32O2Si
• Molecular Weight: 284.514
• Hs Code.: 2931900090
• Mol file: 22414-62-6.mol

Synonyms:Tributylsilyl 2-methylacrylate;Tributylsilyl methacrylate;Silanol, tributyl-, methacrylate (8CI);Methacrylicacid, tributylsilyl ester (8CI);Tri-n-butyl silyl methacrylate;Tributylsilyl 2-methylprop-2-enoate;

Chemical Property of TRI-N-BUTYL SILYL METHACRYLATE

Chemical Property:

• Vapor Pressure: 0mmHg at 25°C
• Refractive Index: 1.441
• Boiling Point: 314.513 °C at 760 mmHg
• Flash Point: 119.714 °C
• PSA: 26.30000
• Density: 0.871 g/cm³
• LogP: 5.45150

Purity/Quality:

98%,99%, ^*data from raw suppliers

TRI-N-BUTYL SILYL METHACRYLATE 95.00% ^*data from reagent suppliers

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

Technology Process of TRI-N-BUTYL SILYL METHACRYLATE

There total 8 articles about TRI-N-BUTYL SILYL METHACRYLATE which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 95.0%

Tributylmethoxysilane (15811-64-0) + methacryloyl anhydride (760-93-0) → tributylsilyl methacrylate (22414-62-6) + methacrylic acid methyl ester (80-62-6,114512-63-9,143476-91-9,25188-98-1,9011-14-7)

Guidance literature:

With Amberlyst 15; at 75 ℃;

DOI:10.1080/00397910701462757

Reference yield: 89.0%

poly(methacrylic acid) (79-41-4,25087-26-7,50867-57-7) + Tributylmethoxysilane (15811-64-0) → methanol (67-56-1) + tributylsilyl methacrylate (22414-62-6)

Guidance literature:

With 4-methoxy-phenol; N,N-dimethyl-formamide; In n-heptane; at 150 - 170 ℃; under 760.051 Torr; Azeotropic distillation;

Reference yield: 79.0%

poly(methacrylic acid) (79-41-4,25087-26-7,50867-57-7) + tributylsilane (998-41-4) → tributylsilyl methacrylate (22414-62-6)

Guidance literature:

With triphenylphosphine; In N,N-dimethyl-formamide; at 20 ℃; for 15h;

DOI:10.1080/00397910701465669

upstream raw materials:

poly(methacrylic acid)

tributylsilane

Tributylmethoxysilane

methacryloyl anhydride

Refernces

• 1、 Liu, Guo-Bin,Zhao, Hong-Yun,Thiemann, Thies. "Triphenylphosphine-catalyzed dehydrogenative coupling reaction of carboxylic acids with silanes - A convenient method for the preparation of silyl esters". . p. 807 - 811. Retrieved 2008/03/27.
• 2、 Liu, Guo-Bin. "Preparation of silyl esters by ZnCl2-catalyzed dehydrogenative cross-coupling of carboxylic acids and silanes". . p. 1431 - 1433. Retrieved 2007/10/03.