1,3-BIS(CHLORODIMETHYLSILYL)PROPANE

Base Information

• Chemical Name: 1,3-BIS(CHLORODIMETHYLSILYL)PROPANE
• CAS No.: 2295-06-9
• Molecular Formula: C7H18Cl2Si2
• Molecular Weight: 229.29
• Hs Code.: 2931900090
• Mol file: 2295-06-9.mol

Synonyms:1,3-Bis(chlorodimethylsilyl)propane;2,6-Disilaheptane,2,6-dichloro-2,6-dimethyl- (7CI,8CI);Silane,1,3-propanediylbis[chlorodimethyl- (9CI);

Chemical Property of 1,3-BIS(CHLORODIMETHYLSILYL)PROPANE

Chemical Property:

• Vapor Pressure: 0.193mmHg at 25°C
• Melting Point: 118 °C
• Refractive Index: 1.4647
• Boiling Point: 217.7 °C at 760 mmHg
• Flash Point: 79.5 °C
• PSA: 0.00000
• Density: 0.962 g/cm³
• LogP: 4.26430

Purity/Quality:

99.5% ^*data from raw suppliers

1,3-BIS(CHLORODIMETHYLSILYL)PROPANE 95.00% ^*data from reagent suppliers

Safty Information:

• Statements: 34
• Safety Statements: 26-36/37/39

MSDS Files:

SDS file from LookChem

Useful:

Technology Process of 1,3-BIS(CHLORODIMETHYLSILYL)PROPANE

There total 8 articles about 1,3-BIS(CHLORODIMETHYLSILYL)PROPANE which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 88.0%

dimethylmonochlorosilane (1066-35-9) + Allylchlorodimethylsilane (4028-23-3) → 1,3-bis(chlorodimethylsilyl)propane (2295-06-9)

Guidance literature:

With platinum⁽⁰⁾-1,3-divinyl-1,1,3,3-tetramethyldisiloxane complex; In toluene; for 2h; Inert atmosphere; Reflux; Schlenk technique;

DOI:10.1055/s-0036-1591925

Reference yield: 87.0%

1,3-bis(trimethylsilyl)propane (2295-05-8) → 1,3-bis(chlorodimethylsilyl)propane (2295-06-9)

Guidance literature:

With chloro-trimethyl-silane; aluminium trichloride;

Reference yield:

chlorodimethyl<3-(dimethylsilyl)propyl>silane (2295-08-1) → 1,3-bis(chlorodimethylsilyl)propane (2295-06-9)

Guidance literature:

With N-chloro-succinimide; In tetrachloromethane; Heating;

DOI:10.1021/jo01019a027

upstream raw materials:

dimethylmonochlorosilane

Allylchlorodimethylsilane

Si,Si'-difluoro-Si,Si,Si',Si'-tetramethyl-Si,Si'-propanediyl-bis-silane

chlorodimethyl<3-(dimethylsilyl)propyl>silane

Downstream raw materials:

1,1,3,3-tetramethyl-2-phenyl-1,3,2-disilaphosphorinane

chlorodimethyl(3-propyl)silane

1,1,2,3,3-pentamethyl-2-phenyl-1,2,3-trisilacyclohexane

dimethyl(phenylethynyl)<3-(dimethylsilyl)propyl>silane

Refernces

• 1、 Lamm, Jan-Hendrik,Niermeier, Philipp,K?rte, Leif A.,Neumann, Beate,Stammler, Hans-Georg,Mitzel, Norbert W.. "Improved Access to 1,8-Dichloro-10-(ethynyl)anthracene: A Useful Building Block for (Semi-)rigid Organic Frameworks". . p. 2009 - 2018. Retrieved 2018.
• 2、 Niermeier, Philipp,Lamm, Jan-Hendrik,Linnemannst?ns, Marvin,Neumann, Beate,Stammler, Hans-Georg,Mitzel, Norbert W.. "Syntheses, Solid State Structures and Photochemistry of α,ω-Bis-[(1,8-dichloroanthracen-10-yl)dimethylsilyl]alkanes". supporting information. p. 3041 - 3047. Retrieved 2018/06/12.