IrCl(CO)Rh(CO)2(CH₃CO₂C₂CO₂CH₃)(((C₆H₅)2P)2CH₂)2⁽¹⁺⁾*ClO₄^(1-)*0.5CH₂Cl₂

Base Information

• Chemical Name: IrCl(CO)Rh(CO)2(CH₃CO₂C₂CO₂CH₃)(((C₆H₅)2P)2CH₂)2⁽¹⁺⁾*ClO₄^(1-)*0.5CH₂Cl₂
• CAS No.: 100815-14-3
• Molecular Formula: 0CH₂Cl₂*C₅₉H₅₀ClIrO₇P₄Rh*ClO₄
• Molecular Weight: 1467.43
• Mol file: 100815-14-3.mol

Synonyms:IrCl(CO)Rh(CO)2(CH₃CO₂C₂CO₂CH₃)(((C₆H₅)2P)2CH₂)2⁽¹⁺⁾*ClO₄^(1-)*0.5CH₂Cl₂

Chemical Property of IrCl(CO)Rh(CO)2(CH₃CO₂C₂CO₂CH₃)(((C₆H₅)2P)2CH₂)2⁽¹⁺⁾*ClO₄^(1-)*0.5CH₂Cl₂

Chemical Property:

Purity/Quality:

99% ，98% ^*data from raw suppliers

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of IrCl(CO)Rh(CO)2(CH₃CO₂C₂CO₂CH₃)(((C₆H₅)2P)2CH₂)2⁽¹⁺⁾*ClO₄^(1-)*0.5CH₂Cl₂

There total 2 articles about IrCl(CO)Rh(CO)2(CH₃CO₂C₂CO₂CH₃)(((C₆H₅)2P)2CH₂)2⁽¹⁺⁾*ClO₄^(1-)*0.5CH₂Cl₂ which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 80.0%

IrCl(CO)RhCl(CO)(CH3OCOC2CO2CH3)(((C6H5)2P)2CH2)2 (100896-61-5) + IrCl(CO)RhCl(CO)(CH3OCOC2CO2CH3)(((C6H5)2P)2CH2)2*0.5CH2Cl2 (100815-11-0) + silver perchlorate → IrCl(CO)Rh(CO)2(CH3CO2C2CO2CH3)(((C6H5)2P)2CH2)2(1+)*ClO4(1-)*0.5CH2Cl2 (100815-14-3)

Guidance literature:

With carbon monoxide; In tetrahydrofuran; dichloromethane; addn. of AgClO4 to susp. of complex, stirring for 0.5 h under slow stream of CO; filtn. through diatomaceous earth under CO, addn. of Et2O and hexane, filtn., washing (Et2O), drying in CO stream, elem. anal.;

DOI:10.1021/om00136a014

Reference yield:

Ir(CO)2RhCl(CH3CO2C2CO2CH3)(((C6H5)2P)2CH2)2(1+)*ClO4(1-)*0.5CH2Cl2 (100815-16-5) → IrCl(CO)Rh(CO)2(CH3CO2C2CO2CH3)(((C6H5)2P)2CH2)2(1+)*ClO4(1-)*0.5CH2Cl2 (100815-14-3)

Guidance literature:

With carbon monoxide; In dichloromethane; CO was purged through soln. of complex at room temp.; elem. anal.;

DOI:10.1021/om00136a014

Reference yield:

IrCl(CO)Rh(CO)2(CH3CO2C2CO2CH3)(((C6H5)2P)2CH2)2(1+)*ClO4(1-)*0.5CH2Cl2 (100815-14-3) → Ir(CO)2RhCl(CH3CO2C2CO2CH3)(((C6H5)2P)2CH2)2(1+)*ClO4(1-)*0.5CH2Cl2 (100815-16-5)

Guidance literature:

In dichloromethane; purging N2 through soln. of complex for 1 h causing color change from purplish brown to dark red; diln. with Et2O, filtn., elem. anal.;

DOI:10.1021/om00136a014

upstream raw materials:

IrCl(CO)RhCl(CO)(CH₃OCOC₂CO₂CH₃)(((C₆H₅)2P)2CH₂)2

IrCl(CO)RhCl(CO)(CH₃OCOC₂CO₂CH₃)(((C₆H₅)2P)2CH₂)2*0.5CH₂Cl₂

Ir(CO)2RhCl(CH₃CO₂C₂CO₂CH₃)(((C₆H₅)2P)2CH₂)2⁽¹⁺⁾*ClO₄^(1-)*0.5CH₂Cl₂

Downstream raw materials:

Ir(CO)2RhCl(CH₃CO₂C₂CO₂CH₃)(((C₆H₅)2P)2CH₂)2⁽¹⁺⁾*ClO₄^(1-)*0.5CH₂Cl₂

Refernces