(1,2-METHANOFULLERENE C60)-61-CARBOXYLIC ACID

Base Information

• Chemical Name: (1,2-METHANOFULLERENE C60)-61-CARBOXYLIC ACID
• CAS No.: 155116-19-1
• Molecular Formula: C62H2 O2
• Molecular Weight: 778.697
• Mol file: 155116-19-1.mol

Synonyms:(1,2-METHANOFULLERENE C60)-61-CARBOXYLIC ACID;(1,2-METHANOFULLERENE C(60))-61-CARBOXY;(1 2-METHANOFULLERENE C(60))-61-CARBO- &

Chemical Property of (1,2-METHANOFULLERENE C60)-61-CARBOXYLIC ACID

Chemical Property:

• Refractive Index: 2.316
• PKA: 4.71±0.20(Predicted)
• PSA: 37.30000
• Density: 2.05g/cm³
• LogP: 16.00840

Purity/Quality:

98%,99%, ^*data from raw suppliers

(1,2-Methanofullerene C60)-61-carboxylic acid 97% (HPLC) ^*data from reagent suppliers

Safty Information:

• Hazard Codes: Xi
• Statements: 36/37/38
• Safety Statements: 26-36

MSDS Files:

SDS file from LookChem

Total 1 MSDS from other Authors

Useful:

• Uses: Reagent for preparation of fullerene derivatives. Interaction of C60 fullerence derivative with L-histidine was studied in detail. The quantum chemical calculations were focused on the enantioselective binding between the two. (1,2-Methanofullerene C60)-61-carboxylic acid may find potential application in biomedical and cosmetics.

Technology Process of (1,2-METHANOFULLERENE C60)-61-CARBOXYLIC ACID

There total 4 articles about (1,2-METHANOFULLERENE C60)-61-CARBOXYLIC ACID which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 100.0%

di-tert-butyl methano[60]fullerene-61,61-dicarboxylate → 1,2-dihydro-1,2-methanofullerene[60]-61-carboxylic acid (155116-19-1)

Guidance literature:

In 1,2-dichloro-benzene; at 180 ℃; for 6h;

DOI:10.1021/jacs.7b08113

Reference yield: 94.0%

tert-butyl 3′H-cyclopropa[1,9](C60-Ih)[5,6]fullerene-3′-carboxylate (150493-29-1) → 1,2-dihydro-1,2-methanofullerene[60]-61-carboxylic acid (155116-19-1)

Guidance literature:

With trifluoroacetic acid; In chloroform; at 65 ℃; for 2h;

DOI:10.1021/ja071803q

Reference yield:

diphenylmethyl 3′H-cyclopropa[1,9](C60-Ih)[5,6]fullerene-3′-carboxylate → 1,2-dihydro-1,2-methanofullerene[60]-61-carboxylic acid (155116-19-1)

Guidance literature:

With toluene-4-sulfonic acid; In 1,2-dichloro-benzene; Heating;

DOI:10.1134/S107042801607023X

upstream raw materials:

tert-butyl 3′H-cyclopropa[1,9](C₆₀-I_h)[5,6]fullerene-3′-carboxylate

Downstream raw materials:

ethyl 3′H-cyclopropa[1,9](C₆₀-I_h)[5,6]fullerene-3′-carboxylate

C₇₅H₁₆O₂

C₈₀H₃₀O₉

C₈₆H₄₄O₉Si

Refernces

• 1、 Sun, Ya-Ping,Lawson, Glenn E.,Riggs, Jason E.,Ma, Bin,Wang, Naixing,Moton, Dwella K.. "Photophysical and nonlinear optical properties of [60]fullerene derivatives". . p. 5520 - 5528. Retrieved 1998.
• 2、 Nikolaev,Davidovich,Piotrovskii. "Synthesis of fullerene C60monoadducts. Cyclopropanation of C60with sulfonium ylides". . p. 1050 - 1053. Retrieved 2016/09/04.