2,3,6,7,10,11-Hexahydroxytriphenylene

Base Information

• Chemical Name: 2,3,6,7,10,11-Hexahydroxytriphenylene
• CAS No.: 4877-80-9
• Molecular Formula: C18H12O6
• Molecular Weight: 324.29
• Hs Code.: 29072990
• European Community (EC) Number: 680-012-6
• DSSTox Substance ID: DTXSID10454818
• Nikkaji Number: J584.219K
• Wikidata: Q72482100
• Mol file: 4877-80-9.mol

Synonyms:2,3,6,7,10,11-Hexahydroxytriphenylene;Triphenylene-2,3,6,7,10,11-hexol;

Chemical Property of 2,3,6,7,10,11-Hexahydroxytriphenylene

Chemical Property:

• Vapor Pressure: 0mmHg at 25°C
• Melting Point: >300oC
• Refractive Index: 1.998
• Boiling Point: 776.272 °C at 760 mmHg
• PKA: 8.46±0.30(Predicted)
• Flash Point: 374.527 °C
• PSA: 121.38000
• Density: 1.778 g/cm³
• LogP: 3.37980
• Storage Temp.: Inert atmosphere,Room Temperature
• Solubility.: very slightly in Tetrahydrofuran
• XLogP3: 2.7
• Hydrogen Bond Donor Count: 6
• Hydrogen Bond Acceptor Count: 6
• Rotatable Bond Count: 0
• Exact Mass: 324.06338810
• Heavy Atom Count: 24
• Complexity: 364

Purity/Quality:

98%,99%, ^*data from raw suppliers

Triphenylene-2,3,6,7,10,11-hexaol ^*data from reagent suppliers

Safty Information:

• Statements: 36/37/38
• Safety Statements: 26-36/37/39

MSDS Files:

SDS file from LookChem

Useful:

• Canonical SMILES: C1=C2C3=CC(=C(C=C3C4=CC(=C(C=C4C2=CC(=C1O)O)O)O)O)O

Technology Process of 2,3,6,7,10,11-Hexahydroxytriphenylene

There total 7 articles about 2,3,6,7,10,11-Hexahydroxytriphenylene which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 100.0%

2,3,6,7,10,11-hexamethoxytriphenylene (808-57-1) → 2,3,6,7,10,11-hexahydroxytriphenylene (4877-80-9)

Guidance literature:

With boron tribromide; In dichloromethane; at -70 - 20 ℃;

DOI:10.1039/b202677e

Reference yield: 96.0%

2,7,12-tri(1,1-dimethylethyl)-2,7,12-trimethyltriphenyleno[2,3-d:6,7-d':10,11-d'']-tris[1,3]dioxole (1415815-64-3) → 2,3,6,7,10,11-hexahydroxytriphenylene (4877-80-9)

Guidance literature:

With water; hydrogen bromide; In acetic acid; for 24h; Reflux;

DOI:10.3762/bjoc.8.196

Reference yield: 93.0%

C54H98O6Si6 (1206881-88-0) → 2,3,6,7,10,11-hexahydroxytriphenylene (4877-80-9)

Guidance literature:

With tetrabutyl ammonium fluoride; In tetrahydrofuran; at 20 ℃; for 2h;

DOI:10.1021/ol902861b

upstream raw materials:

2,3,6,7,10,11-hexamethoxytriphenylene

benzene-1,2-diol

C₅₄H₉₈O₆Si₆

2,7,12-tri(1,1-dimethylethyl)-2,7,12-trimethyltriphenyleno[2,3-d:6,7-d':10,11-d'']-tris[1,3]dioxole

Downstream raw materials:

triphenylene hexa-n-nonanoate

5-bromo-2-(decyloxy)-1,3-dimethylbenzene

Refernces

• 1、 Hao, Dandan,Zhang, Jinna,Lu, Hui,Leng, Wenguang,Ge, Rile,Dai, Xiaonan,Gao, Yanan. "Fabrication of a COF-5 membrane on a functionalized α-Al 2O3 ceramic support using a microwave irradiation method". . p. 1462 - 1464. Retrieved 2014.
• 2、 Xue,Agarwal,Zhang,Staal,Mueller,Bailly,Lemstra. "Synthesis and direct topology visualization of high-molecular-weight star PMMA". . p. 2093 - 2100. Retrieved 2005.
• 3、 Zniber, Rachid,Achour, Redouane,Cherkaoui, Mohammed Zoubair,Donnio, Bertrand,Gehringer, Lionel,Guillon, Daniel. "Columnar mesophase from a new hybrid siloxane-triphenylene". . p. 2208 - 2213. Retrieved 2002.
• 4、 Herbaut, Antoine,Baranoff, Etienne. "UV-visible absorption study of the selfassociation of non-ionic chromonic triphenylenes TP6EOnM (n = 2, 3, 4) in dilute aqueous solutions: Impact of chain length on aggregation". . p. 520 - 523. Retrieved 2015.
• 5、 Morimoto, Koji,Dohi, Toshifumi,Kita, Yasuyuki. "Oxidative trimerization of catechol to hexahydroxytriphenylene". . p. 1659 - 1662. Retrieved 2013.
• 6、 Hamzehpoor, Ehsan,Jonderian, Antranik,McCalla, Eric,Perepichka, Dmitrii F.. "Synthesis of Boroxine and Dioxaborole Covalent Organic Frameworks via Transesterification and Metathesis of Pinacol Boronates". supporting information. p. 13274 - 13280. Retrieved 2021/09/07.
• 7、 -. "Discotic liquid crystal epoxy resin monomer and preparation method thereof, and intrinsic high-thermal-conductivity liquid crystal epoxy resin material and preparation method thereof". Paragraph 0084; 0086. . Retrieved 2021/08/11.