pent-1-ene-2,4-diyldibenzene

Base Information

• Chemical Name: pent-1-ene-2,4-diyldibenzene
• CAS No.: 38212-18-9
• Molecular Formula: C₁₇H₁₈
• Molecular Weight: 222.33
• Mol file: 38212-18-9.mol

Synonyms:pent-1-ene-2,4-diyldibenzene

Chemical Property of pent-1-ene-2,4-diyldibenzene

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of pent-1-ene-2,4-diyldibenzene

There total 10 articles about pent-1-ene-2,4-diyldibenzene which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 89.0%

ethylbenzene (100-41-4,27536-89-6) + 2-((2-phenylallyl)oxy)isoindoline-1,3-dione (1608461-37-5) → N-hydroxyphthalimide (524-38-9) + pent-1-ene-2,4-diyldibenzene (38212-18-9)

Guidance literature:

With di-tert-butyl peroxide; In neat (no solvent); at 120 ℃; for 29h;

DOI:10.1002/ejoc.201301530

Reference yield: 89.0%

ethylbenzene (100-41-4,27536-89-6) + 2-((2-phenylallyl)oxy)isoindoline-1,3-dione (1608461-37-5) → pent-1-ene-2,4-diyldibenzene (38212-18-9)

Guidance literature:

With di-tert-butyl peroxide; In neat (no solvent); at 120 ℃; for 29h; Sealed tube;

DOI:10.1002/ejoc.201301530

Reference yield: 57.0%

[3-(benzenesulfonyl)prop-1-en-2-yl]benzene (74866-37-8) + 2-(1-phenylethoxy)isoindoline-1,3-dione (172789-09-2) → pent-1-ene-2,4-diyldibenzene (38212-18-9)

Guidance literature:

2-(1-phenylethoxy)isoindoline-1,3-dione; With (4,4'-di-tert-butyl-2,2'-dipyridyl)-bis-(2-phenylpyridine(-1H))-iridium(III) hexafluorophosphate; diethyl 2,6-dimethyl-1,4-dihydropyridine-3,5-dicarboxylate; at 20 ℃; for 0.166667h; Schlenk technique; Inert atmosphere;

[3-(benzenesulfonyl)prop-1-en-2-yl]benzene; With phosphorous acid trimethyl ester; In tert-butyl methyl ether; at 20 ℃; for 12h; Inert atmosphere; Schlenk technique; Irradiation;

DOI:10.1002/chem.201806138

upstream raw materials:

styrene

isopropenylbenzene

ethylbenzene

2-((2-phenylallyl)oxy)isoindoline-1,3-dione

Refernces

• 1、 Han, Jia-Bin,Guo, Ao,Tang, Xiang-Ying. "Alkylation of Allyl/Alkenyl Sulfones by Deoxygenation of Alkoxyl Radicals". supporting information. p. 2989 - 2994. Retrieved 2019/02/05.
• 2、 Patil, Shradha,Chen, Liang,Tanko, James M.. "C-H Bond Functionalization with the Formation of a C-C Bond: A Free Radical Condensation Reaction Based on the Phthalimido-N-oxyl Radical". supporting information. p. 502 - 505. Retrieved 2015/10/05.