B(C₆H₅)2C₄H₃NCHNC₆H₅

Base Information

• Chemical Name: B(C₆H₅)2C₄H₃NCHNC₆H₅
• CAS No.: 1386987-99-0
• Molecular Formula: C₂₃H₁₉BN₂
• Molecular Weight: 334.228
• Mol file: 1386987-99-0.mol

Synonyms:B(C₆H₅)2C₄H₃NCHNC₆H₅

Chemical Property of B(C₆H₅)2C₄H₃NCHNC₆H₅

Chemical Property:

Purity/Quality:

Safty Information:

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MSDS Files:

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Technology Process of B(C₆H₅)2C₄H₃NCHNC₆H₅

There total 3 articles about B(C₆H₅)2C₄H₃NCHNC₆H₅ which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 80.0%

N-pyrrol-2-ylmethylene-aniline (4089-09-2) + triphenylborane (960-71-4) → B(C6H5)2C4H3NCHNC6H5 (1386987-99-0)

Guidance literature:

In toluene; Inert atmosphere; Reflux;

DOI:10.1039/c2dt30487b

Reference yield: 58.0%

N-pyrrol-2-ylmethylene-aniline (4089-09-2) + phenylboronic acid (98-80-6) → B(C6H5)2C4H3NCHNC6H5 (1386987-99-0)

Guidance literature:

With potassium phosphate; In 1,4-dioxane; Reflux;

Reference yield:

2-pyrrole aldehyde (1003-29-8,254729-95-8) + aniline (62-53-3) → B(C6H5)2C4H3NCHNC6H5 (1386987-99-0)

Guidance literature:

Multi-step reaction with 2 steps

1: toluene-4-sulfonic acid; magnesium sulfate / ethanol / Inert atmosphere; Schlenk technique; Reflux

2: toluene / Reflux; Inert atmosphere; Schlenk technique

With magnesium sulfate; toluene-4-sulfonic acid; In ethanol; toluene;

DOI:10.1002/chem.201303607

upstream raw materials:

N-pyrrol-2-ylmethylene-aniline

triphenylborane

2-pyrrole aldehyde

aniline

Refernces

• 1、 Suresh,Lopes, Patricia S.,Ferreira, Bruno,Figueira, Claudia A.,Gomes, Clara S. B.,Gomes, Pedro T.,Di Paolo, Roberto E.,MacAnita, Antonio L.,Duarte, M. Teresa,Charas, Ana,Morgado, Jorge,Calhorda, Maria Jose. "Tunable fluorophores based on 2-(N-Arylimino)pyrrolyl chelates of diphenylboron: Synthesis, structure, photophysical characterization, and application in OLEDs". . p. 4126 - 4140. Retrieved 2014/04/17.
• 2、 Suresh,Gomes, Clara S. B.,Gomes, Pedro T.,Di Paolo, Roberto E.,Ma?Anita, António L.,Calhorda, Maria José,Charas, Ana,Morgado, Jorge,Teresa Duarte. "Syntheses and photophysical properties of new iminopyrrolyl boron complexes and their application in efficient single-layer non-doped OLEDs prepared by spin coating". supporting information; experimental part. p. 8502 - 8505. Retrieved 2012/10/08.