4,4'-bis((3-(2-methacryloyloxyethoxy)methyl)-4-methoxyphenyl)diphenyl sulfone

Base Information

• Chemical Name: 4,4'-bis((3-(2-methacryloyloxyethoxy)methyl)-4-methoxyphenyl)diphenyl sulfone
• CAS No.: 1349857-00-6
• Molecular Formula: C₄₀H₄₂O₁₀S
• Molecular Weight: 714.833
• Mol file: 1349857-00-6.mol

Synonyms:4,4'-bis((3-(2-methacryloyloxyethoxy)methyl)-4-methoxyphenyl)diphenyl sulfone

Chemical Property of 4,4'-bis((3-(2-methacryloyloxyethoxy)methyl)-4-methoxyphenyl)diphenyl sulfone

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of 4,4'-bis((3-(2-methacryloyloxyethoxy)methyl)-4-methoxyphenyl)diphenyl sulfone

There total 6 articles about 4,4'-bis((3-(2-methacryloyloxyethoxy)methyl)-4-methoxyphenyl)diphenyl sulfone which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 55.0%

methacryloyl anhydride (760-93-0) + C32H34O8S (1349856-97-8) → 4,4'-bis((3-(2-methacryloyloxyethoxy)methyl)-4-methoxyphenyl)diphenyl sulfone (1349857-00-6)

Guidance literature:

With pyridine; dmap; 4-methoxy-phenol; In chloroform; at 20 ℃; for 12h;

Reference yield:

4,4'-sulfonediphenol (80-09-1,59790-00-0) → 4,4'-bis((3-(2-methacryloyloxyethoxy)methyl)-4-methoxyphenyl)diphenyl sulfone (1349857-00-6)

Guidance literature:

Multi-step reaction with 6 steps

1.1: triethylamine / chloroform / 6 h / 0 - 20 °C

2.1: sodium hydrogencarbonate / tetrakis(triphenylphosphine) palladium⁽⁰⁾ / 1,4-dioxane; water / 3 h / 80 °C

3.1: sodium tetrahydroborate; methanol / tetrahydrofuran / 0 °C

3.2: 2 h / 20 °C

4.1: sodium hydride / N,N-dimethyl-formamide; mineral oil / 1 h / 0 - 20 °C

4.2: 6 h / 70 °C

5.1: toluene-4-sulfonic acid; methanol / tetrahydrofuran / 12 h / 20 °C

6.1: dmap; 4-methoxy-phenol; pyridine / chloroform / 12 h / 20 °C

With pyridine; methanol; dmap; sodium tetrahydroborate; sodium hydride; sodium hydrogencarbonate; toluene-4-sulfonic acid; 4-methoxy-phenol; triethylamine; tetrakis(triphenylphosphine) palladium⁽⁰⁾; In tetrahydrofuran; 1,4-dioxane; chloroform; water; N,N-dimethyl-formamide; mineral oil;

Reference yield:

4,4'-sulfonylbis(phenyltrifluoromethanesulfonate) (17763-90-5) → 4,4'-bis((3-(2-methacryloyloxyethoxy)methyl)-4-methoxyphenyl)diphenyl sulfone (1349857-00-6)

Guidance literature:

Multi-step reaction with 5 steps

1.1: sodium hydrogencarbonate / tetrakis(triphenylphosphine) palladium⁽⁰⁾ / 1,4-dioxane; water / 3 h / 80 °C

2.1: sodium tetrahydroborate; methanol / tetrahydrofuran / 0 °C

2.2: 2 h / 20 °C

3.1: sodium hydride / N,N-dimethyl-formamide; mineral oil / 1 h / 0 - 20 °C

3.2: 6 h / 70 °C

4.1: toluene-4-sulfonic acid; methanol / tetrahydrofuran / 12 h / 20 °C

5.1: dmap; 4-methoxy-phenol; pyridine / chloroform / 12 h / 20 °C

With pyridine; methanol; dmap; sodium tetrahydroborate; sodium hydride; sodium hydrogencarbonate; toluene-4-sulfonic acid; 4-methoxy-phenol; tetrakis(triphenylphosphine) palladium⁽⁰⁾; In tetrahydrofuran; 1,4-dioxane; chloroform; water; N,N-dimethyl-formamide; mineral oil;

upstream raw materials:

methacryloyl anhydride

C₃₂H₃₄O₈S

4,4'-sulfonediphenol

4,4'-bis(3-hydroxymethyl-4-methoxyphenyl)diphenyl sulfone

Refernces