diallyl 2-(2-nitrophenyl)malonate

Base Information

• Chemical Name: diallyl 2-(2-nitrophenyl)malonate
• CAS No.: 930101-15-8
• Molecular Formula: C₁₅H₁₅NO₆
• Molecular Weight: 305.287
• Mol file: 930101-15-8.mol

Synonyms:diallyl 2-(2-nitrophenyl)malonate

Chemical Property of diallyl 2-(2-nitrophenyl)malonate

Chemical Property:

Purity/Quality:

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• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

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Technology Process of diallyl 2-(2-nitrophenyl)malonate

There total 1 articles about diallyl 2-(2-nitrophenyl)malonate which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 89.0%

diallyl malonate (1797-75-7) + ortho-nitrofluorobenzene (1493-27-2,127723-77-7) → diallyl 2-(2-nitrophenyl)malonate (930101-15-8)

Guidance literature:

With potassium carbonate; In N,N-dimethyl-formamide; at 90 ℃; for 16h; Inert atmosphere;

DOI:10.1021/ol5013263

Reference yield: 95.0%

diallyl 2-(2-nitrophenyl)malonate (930101-15-8) + C19H29Br2NO2Si → C34H43BrN2O8Si

Guidance literature:

With caesium carbonate; In tetrahydrofuran; at 0 ℃; for 1h; Inert atmosphere;

DOI:10.1021/ol5013263

Reference yield: 88.0%

diallyl 2-(2-nitrophenyl)malonate (930101-15-8) + methyl iodide (74-88-4) → diallyl 2-methyl-2-(2-nitrophenyl)malonate (930101-03-4)

Guidance literature:

diallyl 2-(2-nitrophenyl)malonate; With sodium hydride; In N,N-dimethyl-formamide; cooling;

methyl iodide; In N,N-dimethyl-formamide; at 55 ℃;

DOI:10.1021/jo0621569

upstream raw materials:

diallyl malonate

ortho-nitrofluorobenzene

Downstream raw materials:

diallyl 2-methyl-2-(2-nitrophenyl)malonate

Refernces

• 1、 Imao, Daisuke,Itoi, Akihiro,Yamazaki, Asako,Shirakura, Masamichi,Ohtoshi, Ryota,Ogata, Kenta,Ohmori, Yohki,Ohta, Tetsuo,Ito, Yoshihiko. "Easy access to esters with a benzylic quaternary carbon center from diallyl malonates by palladium-catalyzed decarboxylative allylation". . p. 1652 - 1658. Retrieved 2007/10/03.