4,4'-Methylenebis(benzenesulfonyl chloride)

Base Information

• Chemical Name: 4,4'-Methylenebis(benzenesulfonyl chloride)
• CAS No.: 3119-64-0
• Molecular Formula: C13H10Cl2O4S2
• Molecular Weight: 365.258
• Hs Code.: 2904909090
• European Community (EC) Number: 621-897-0
• DSSTox Substance ID: DTXSID30391877
• Nikkaji Number: J308.149D
• Wikidata: Q82189641
• Mol file: 3119-64-0.mol

Synonyms:3119-64-0;4,4'-Methylenebis(benzenesulfonyl chloride);4-[(4-chlorosulfonylphenyl)methyl]benzenesulfonyl Chloride;4,4-METHYLENEBIS(BENZENESULFONYLCHLORIDE);4,4-METHYLENEBIS(BENZENESULFONYL CHLORIDE);4-[4-(Chlorosulfonyl)benzyl]-benzenesulfonyl chloride;Benzenesulfonyl chloride, 4,4'-methylenebis-;SCHEMBL2263958;DTXSID30391877;Bis(4-chlorosulfonylphenyl)methane;MFCD00012363;AKOS015889339;4,4'-methylenedibenzene-1-sulfonyl chloride;FT-0634678;M1556;4,4'-Methylenedi(benzene-1-sulfonyl chloride);T72275;4,4'-Methylenebis(benzenesulfonyl chloride), 97%;4-[4-(Chlorosulfonyl)benzyl]benzenesulfonyl chloride;J-018276

Chemical Property of 4,4'-Methylenebis(benzenesulfonyl chloride)

Chemical Property:

• Melting Point: 123-125 °C(lit.)
• Boiling Point: 483.9±38.0 °C(Predicted)
• Flash Point: 246.4oC
• PSA: 85.04000
• Density: 1.508±0.06 g/cm3(Predicted)
• LogP: 5.29400
• Storage Temp.: 2-8°C
• XLogP3: 3.9
• Hydrogen Bond Donor Count: 0
• Hydrogen Bond Acceptor Count: 4
• Rotatable Bond Count: 4
• Exact Mass: 363.9397565
• Heavy Atom Count: 21
• Complexity: 482

Purity/Quality:

98%,99%, ^*data from raw suppliers

4-[4-(Chlorosulfonyl)benzyl]benzenesulfonylChloride ^*data from reagent suppliers

Safty Information:

• Hazard Codes: C
• Statements: 20/21/22-34
• Safety Statements: 23-26-27-36/37/39-45

MSDS Files:

SDS file from LookChem

Total 1 MSDS from other Authors

Useful:

• Canonical SMILES: C1=CC(=CC=C1CC2=CC=C(C=C2)S(=O)(=O)Cl)S(=O)(=O)Cl
• Uses: 4,4′-Methylenebis(benzenesulfonyl chloride) [(Diphenylmethane-4,4′-disulfonyl chloride)] was used in the synthesis of polymers representing the aromatic piperazine sulfonamide to study their thermal stability.

Technology Process of 4,4'-Methylenebis(benzenesulfonyl chloride)

There total 3 articles about 4,4'-Methylenebis(benzenesulfonyl chloride) which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 83.0%

Diphenylmethane (101-81-5) → diphenylmethane-4,4'-disulfonyl chloride (3119-64-0)

Guidance literature:

With chlorosulfonic acid; at 20 - 30 ℃;

Reference yield:

chlorosulfonic acid (7790-94-5) + Diphenylmethane (101-81-5) → diphenylmethane-4,4'-disulfonyl chloride (3119-64-0)

Guidance literature:

at 80 ℃;

Reference yield:

→ diphenylmethane-4,4'-disulfonyl chloride (3119-64-0)

Guidance literature:

upstream raw materials:

Diphenylmethane

chlorosulfonic acid

Downstream raw materials:

4,4′-methylenedibenzenethiol

4,4'-methanediyl-bis-benzenesulfonic acid dihydrazide

C₂₁H₂₆N₂O₄S₂

bis-[4-(piperidine-1-sulfonyl)-phenyl]-methane

Refernces

• 1、 Yanota, Kh.,Alov, E. M.,Moskvichev, Yu. A.,Mironov, G. S.. "SYNTHESIS OF BENZOPHENONE-4,4'-DISULFONYL CHLORIDE". . p. 329 - 331. Retrieved 2007/10/02.