N-DODECYLBORONIC ACID

Base Information

• Chemical Name: N-DODECYLBORONIC ACID
• CAS No.: 3088-79-7
• Molecular Formula: C12H27 B O2
• Molecular Weight: 214.156
• Hs Code.: 2931900090
• Mol file: 3088-79-7.mol

Synonyms:1-Dodecaneboronicacid (6CI,7CI,8CI); Boronic acid, dodecyl- (9CI)

Chemical Property of N-DODECYLBORONIC ACID

Chemical Property:

• Vapor Pressure: 1.28E-05mmHg at 25°C
• Melting Point: 91-93°C
• Refractive Index: 1.439
• Boiling Point: 329.8°Cat760mmHg
• PKA: 10.35±0.43(Predicted)
• Flash Point: 153.2°C
• PSA: 40.46000
• Density: 0.879g/cm³
• LogP: 3.38010
• Storage Temp.: 2-8°C
• Sensitive.: Air Sensitive

Purity/Quality:

99% ^*data from raw suppliers

N-Dodecylboronic acid ^*data from reagent suppliers

Safty Information:

• Pictogram(s): R36/37/38:Irritating to eyes, respiratory system and skin.
• Hazard Codes: R36/37/38:Irritating to eyes, respiratory system and skin.
• Statements: 36/37/38
• Safety Statements: 26-36

MSDS Files:

SDS file from LookChem

Useful:

Technology Process of N-DODECYLBORONIC ACID

There total 6 articles about N-DODECYLBORONIC ACID which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 38.0%

1-dodecylbromide (143-15-7) → n-dodecylboronic acid (3088-79-7)

Guidance literature:

1-dodecylbromide; With iodine; magnesium; In diethyl ether; for 2h; Inert atmosphere; Reflux;

With Trimethyl borate; In diethyl ether; at 0 - 20 ℃; Inert atmosphere;

DOI:10.1021/jo201078w

Reference yield:

Trimethyl borate (121-43-7,63156-11-6) + 1-dodecylbromide (143-15-7) → n-dodecylboronic acid (3088-79-7)

Guidance literature:

1-dodecylbromide; With iodine; magnesium; In diethyl ether; for 1h; Reflux; Inert atmosphere;

Trimethyl borate; In tetrahydrofuran; diethyl ether; at -78 - 20 ℃; for 2h; Inert atmosphere;

With hydrogenchloride; water; In tetrahydrofuran; diethyl ether; for 0.25h;

Reference yield:

2-dodecyl-4,4,5,5-tetramethyl-1,3,2-dioxaborolane (177035-82-4) → n-dodecylboronic acid (3088-79-7)

Guidance literature:

With hydrogenchloride; In water; at 70 ℃;

upstream raw materials:

boric acid tributyl ester

dodecylmagnesium chloride

1-dodecylbromide

1-dodecene

Downstream raw materials:

1,1-diphenyl-tetradec-1-ene

4-dodecyl-1-(trimethylsilyl)benzene

1-dodecyl-4-iodobenzene

methyl 5-dodecyl-3-(5-dodecyl-3-(5-dodecyl-3-(5-dodecyl-2-fluoro-3-nitrobenzamido)-2-fluorobenzamido)-2-fluorobenzamido)-2-fluorobenzoate

Refernces

• 1、 -. "FLUORESCENCE DETECTION OF POISON OAK OIL". . . Retrieved 2013/05/22.
• 2、 Ren, Changliang,Xu, Shengyu,Xu, Jun,Chen, Hongyu,Zeng, Huaqiang. "Planar macrocyclic fluoropentamers as supramolecular organogelators". supporting information; experimental part. p. 3840 - 3843. Retrieved 2011/09/19.