CESIUM TETRAPHENYLBORATE

Base Information

• Chemical Name: CESIUM TETRAPHENYLBORATE
• CAS No.: 3087-82-9
• Molecular Formula: C24H20 B . Cs
• Molecular Weight: 452.139
• Hs Code.: 2931900090
• Mol file: 3087-82-9.mol

Synonyms:Borate(1-),tetraphenyl-, cesium (8CI,9CI); Cesium tetraphenylborate (7CI); Cesiumtetraphenylborate(1-)

Chemical Property of CESIUM TETRAPHENYLBORATE

Chemical Property:

• Melting Point: >400 °C(lit.)
• PSA: 0.00000
• LogP: 3.06400

Purity/Quality:

98%,99%, ^*data from raw suppliers

Cesium tetraphenylborate 98% ^*data from reagent suppliers

Safty Information:

• Hazard Codes: Xi
• Statements: 36/37/38
• Safety Statements: 26-37/39

MSDS Files:

SDS file from LookChem

Total 1 MSDS from other Authors

Useful:

• Uses: Reactant for synthesis of:Complexes of alkali metal tetraphenylborates with macrocyclic crown ethers[C6F5Xe]+ salts of weakly coordinating borate anionsAlkali metals with π- and σ-modalities

Technology Process of CESIUM TETRAPHENYLBORATE

There total 6 articles about CESIUM TETRAPHENYLBORATE which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

cesium chloride (15690-63-8,64704-31-0,7647-17-8) + sodium tetraphenyl borate (143-66-8) → cesium tetraphenylborate (3087-82-9)

Guidance literature:

In water; addn. of an aq. soln. of CsCl to NaBPh4 in water, pptn.; filtration, crystn., repeated crystn. (acetone), drying (100 °C);

DOI:10.1016/0040-6031(89)85405-X

Reference yield:

caesium(1+) (18459-37-5,61373-41-9) + sodium tetraphenyl borate (143-66-8) → cesium tetraphenylborate (3087-82-9)

Guidance literature:

In not given; pptn. on mixing;

DOI:10.1016/S0020-1693(00)88745-9

Reference yield:

caesium nitrate + sodium tetraphenyl borate (143-66-8) → cesium tetraphenylborate (3087-82-9)

Guidance literature:

In water; mixing of aq. equimolar soln. of CsNO3 with NaBPh4; recrystn. from acetone-ether, drying for several hours;

upstream raw materials:

cesium chloride

sodium tetraphenyl borate

caesium⁽¹⁺⁾

potassium tetraphenylborate

Downstream raw materials:

4-Methylbiphenyl

Refernces

• 1、 Luo, Qi,Dai, Zengjin,Cong, Hengjiang,Li, Renjie,Peng, Tianyou,Zhang, Jing. "Oxidant-free synthesis of benzimidazoles from alcohols and aromatic diamines catalysed by new Ru(II)-PNS(O) pincer complexes". . p. 15012 - 15022. Retrieved 2017/11/14.
• 2、 Gilkerson, William R.,Kendrick, Katherine L.. "Ion Association. Comparison of Spectroscopic and Conductance Values of Association Constants". . p. 5352 - 5359. Retrieved 2007/10/02.