sodium dimethyl phosphate

Base Information

• Chemical Name: sodium dimethyl phosphate
• CAS No.: 32586-82-6
• Molecular Formula: C2H6NaO4P
• Molecular Weight: 148.031
• Hs Code.: 2919900090
• Mol file: 32586-82-6.mol

Synonyms:sodium dimethyl phosphate

Chemical Property of sodium dimethyl phosphate

Chemical Property:

• Vapor Pressure: 1.28mmHg at 25°C
• Melting Point: >250 °C (decomp)(Solv: acetone (67-64-1))
• Boiling Point: 159.8°Cat760mmHg
• Flash Point: 50.4°C
• PSA: 68.40000
• Density: 1.314g/cm³
• LogP: 0.81780

Purity/Quality:

99% ^*data from raw suppliers

DimethylPhosphateSodiumSalt ^*data from reagent suppliers

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

• Uses: DiMethyl Phosphate SodiuM Salt is used in the synthesis of L,L- and L,D-di-myo-inositolphosphates.

Technology Process of sodium dimethyl phosphate

There total 8 articles about sodium dimethyl phosphate which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 94.0%

trimethyl phosphite (512-56-1) → sodium dimethyl phosphate (32586-82-6)

Guidance literature:

With sodium iodide; In acetone; at 20 ℃; for 72h;

DOI:10.1039/c3ra46749j

Reference yield:

dimethylphosphoric acid (813-78-5) → sodium dimethyl phosphate (32586-82-6)

Guidance literature:

With sodium methylate; In methanol;

Reference yield:

disodium hydrogenphosphate → sodium dimethyl phosphate (32586-82-6) + bis-sodium salt of methyl phosphate (17323-81-8,51528-83-7)

Guidance literature:

With dimethyl sulfate; In water;

upstream raw materials:

trimethyl phosphite

N-(dimethylphosphoryl)ethyleneimine

p-cyanophenyl dimethyl phosphate

4-cyano-2-methylphenyl dimethyl phosphate

Downstream raw materials:

Isophthaloyl bis(dimethyl phosphate)

dimethylphosphorous dimethylphosphoric anhydride

formaldehyd

formic acid

Refernces

• 1、 Hikawa, Hidemasa,Imani, Maki,Suzuki, Hideharu,Yokoyama, Yuusaku,Azumaya, Isao. "Benzoyl methyl phosphates as efficient reagents in the one-pot tandem approach for the synthesis of 2-phenylbenzimidazoles in water". . p. 3768 - 3773. Retrieved 2014/01/06.
• 2、 Tony Liu,Neverov, Alexei A.,Maxwell, Christopher I.,Stan Brown. "Demonstration of prominent Cu(ll)-promoted leaving group stabilization of the cleavage of a homologous set of phosphate Mono-, Di-, and triesters in methanol". supporting information; experimental part. p. 3561 - 3573. Retrieved 2010/05/01.