1-Ethyl-3-methylimidazolium bis(pentafluoroethylsulfonyl)imide

Base Information

• Chemical Name: 1-Ethyl-3-methylimidazolium bis(pentafluoroethylsulfonyl)imide
• CAS No.: 216299-76-2
• Molecular Formula: C6H11N2.C4F10NO4S2
• Molecular Weight: 491.33
• European Community (EC) Number: 801-335-2
• DSSTox Substance ID: DTXSID00583641
• Mol file: 216299-76-2.mol

Synonyms:216299-76-2;1-Ethyl-3-methylimidazolium bis(pentafluoroethylsulfonyl)imide;bis(1,1,2,2,2-pentafluoroethylsulfonyl)azanide;1-ethyl-3-methylimidazol-3-ium;1-Ethyl-3-methylimidazolium bis(pentafluoroethylsulfonyl)imide, 98%;3-Ethyl-1-methyl-1H-imidazol-3-ium bis((perfluoroethyl)sulfonyl)amide;1-Ethyl-3-methyl-1H-imidazol-3-ium bis(pentafluoroethanesulfonyl)azanide;1-ETHYL-3-METHYLIMIDAZOLIUM BIS(PENTAFLUOROETHYLSULFONYL)IMIDE, 99% [EMIBETI];SCHEMBL8080635;DTXSID00583641;SUDHVXIPIDQEIT-UHFFFAOYSA-N;MFCD03788926;AKOS015912424;1-ethyl-3-methylimidazolium bis(perfluoroethylsulfonyl)imide;1-ethyl-3-methyl-1H-imidazol-3-ium bis(perfluoroethylsulfonyl)amide;1-Ethyl-3-methylimidazolium bis(pentafluoroethylsulfonyl)imide [EMIBeti];1-Ethyl-3-methylimidazolium bis(pentafluoroethylsulfonyl)imide,99%[emibeti];1-Ethyl-3-methylimidazolium bis(pentafluoroethylsulfonyl)imide, >=97.0% (H-NMR);1-ETHYL-3-METHYLIMIDAZOLIUMBIS(PENTAFLUOROETHYLSULFONYL)IMIDE,99%[EMIBETI]

Chemical Property of 1-Ethyl-3-methylimidazolium bis(pentafluoroethylsulfonyl)imide

Chemical Property:

• Melting Point: ≤−1 °C(lit.)
• PSA: 93.85000
• Density: 1,57 g/cm3
• LogP: 4.82400
• Hydrogen Bond Donor Count: 0
• Hydrogen Bond Acceptor Count: 15
• Rotatable Bond Count: 5
• Exact Mass: 491.00312981
• Heavy Atom Count: 29
• Complexity: 606

Purity/Quality:

97% ^*data from raw suppliers

1-Ethyl-3-methylimidazolium bis(pentafluoroethylsulfonyl)imide, 99% [EMIBeti] ^*data from reagent suppliers

Safty Information:

• Statements: 36/37/38
• Safety Statements: 26-36/37/39

MSDS Files:

SDS file from LookChem

Total 1 MSDS from other Authors

Useful:

• Canonical SMILES: CCN1C=C[N+](=C1)C.C(C(F)(F)S(=O)(=O)[N-]S(=O)(=O)C(C(F)(F)F)(F)F)(F)(F)F
• Uses: 1-Ethyl-3-methylimidazolium bis(pentafluoroethylsulfonyl)imide can be used:As a model ionic liquid in the preparation of supported ionic liquid membranes (SILMs), which are employed in the studies of CO2?and N2?gas permeation.In the studies of solubility and absorption of 1,1,1,2-tetrafluoroethane, difluoromethane, and fluorinated ethanes in ionic liquids.As a medium for the electro-polymerization?of pyrrole based monomers to yield N-(methyl)phenyl?polypyrroles.

Technology Process of 1-Ethyl-3-methylimidazolium bis(pentafluoroethylsulfonyl)imide

There total 3 articles about 1-Ethyl-3-methylimidazolium bis(pentafluoroethylsulfonyl)imide which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 99.0%

1-methyl-1H-imidazole (616-47-7) + N-ethyl bis(pentafluoroethanesulfonyl)imide (1234568-83-2) → 1-ethyl-3-methylimidazolium bis(pentafluoroethylsulfonyl)imide (216299-76-2)

Guidance literature:

at 75 ℃; for 1h;

Reference yield: 82.0%

3-ethyl-1-methyl-1H-imidazol-3-ium bromide (65039-08-9) + lithium bis((pentafluoroethyl)sulfonyl)amide → 1-ethyl-3-methylimidazolium bis(pentafluoroethylsulfonyl)imide (216299-76-2)

Guidance literature:

In water; at 20 ℃; for 2h;

DOI:10.1039/c7cp06297d

Reference yield:

1-ethyl-3-methyl-1H-imidazol-3-ium chloride (65039-09-0) + lithium bis((pentafluoroethyl)sulfonyl)amide → 1-ethyl-3-methylimidazolium bis(pentafluoroethylsulfonyl)imide (216299-76-2)

Guidance literature:

In dichloromethane; water;

DOI:10.1039/c7cc08449h

upstream raw materials:

1-methyl-1H-imidazole

N-ethyl bis(pentafluoroethanesulfonyl)imide

3-ethyl-1-methyl-1H-imidazol-3-ium bromide

1-ethyl-3-methyl-1H-imidazol-3-ium chloride

Refernces

• 1、 Tsurumaki, Akiko,Ohno, Hiroyuki. "Dissolution of oligo(tetrafluoroethylene) and preparation of poly(tetrafluoroethylene)-based composites by using fluorinated ionic liquids". supporting information. p. 409 - 412. Retrieved 2018/02/27.