1-Chloro-2,2-difluoroethenyl-tributyltin

Base Information

• Chemical Name: 1-Chloro-2,2-difluoroethenyl-tributyltin
• CAS No.: 214422-68-1
• Molecular Formula: C14H27 Cl F2 Sn
• Molecular Weight: 387.5239864
• DSSTox Substance ID: DTXSID10441925
• Mol file: 214422-68-1.mol

Synonyms:214422-68-1;1-Chloro-2,2-difluoroethenyl-tributyltin;AGN-PC-0N6TAY;DTXSID10441925

Chemical Property of 1-Chloro-2,2-difluoroethenyl-tributyltin

Chemical Property:

• PSA: 0.00000
• LogP: 5.71190
• Hydrogen Bond Donor Count: 0
• Hydrogen Bond Acceptor Count: 2
• Rotatable Bond Count: 10
• Exact Mass: 388.079137
• Heavy Atom Count: 18
• Complexity: 228

Purity/Quality:

99% ^*data from raw suppliers

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

• Canonical SMILES: CCCC[Sn](CCCC)(CCCC)C(=C(F)F)Cl

Technology Process of 1-Chloro-2,2-difluoroethenyl-tributyltin

There total 1 articles about 1-Chloro-2,2-difluoroethenyl-tributyltin which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 84.0%

1,1,1-trifluoro-2-chloroethane (75-88-7) + tributyltin chloride (1461-22-9) → tributyl(chlorodifluorovinyl)tin (214422-68-1)

Guidance literature:

With BuLi; In diethyl ether; BuLi added to soln. of ligand in Et2O at -80°C; after 2 h soln. of Bu3SnCl in Et2O (dissolved at -80°C) added slowly at -110°C; warmed to room temp. overnight; hexane added; filtered; solvent removed on rotary evaporator; distd. in vac. (242°C, 0.2 mmHg); elem. anal.;

DOI:10.1016/S0022-328X(00)00565-9

upstream raw materials:

1,1,1-trifluoro-2-chloroethane

tributyltin chloride

Refernces