2-(DIPHENYLPHOSPHINO)-1,3-BENZOTHIAZOLE

Base Information

• Chemical Name: 2-(DIPHENYLPHOSPHINO)-1,3-BENZOTHIAZOLE
• CAS No.: 80679-26-1
• Molecular Formula: C19H14 N P S
• Molecular Weight: 319.367
• Mol file: 80679-26-1.mol

Synonyms:2-(DIPHENYLPHOSPHINO)-1,3-BENZOTHIAZOLE

Chemical Property of 2-(DIPHENYLPHOSPHINO)-1,3-BENZOTHIAZOLE

Chemical Property:

• PSA: 54.72000
• LogP: 4.05450

Purity/Quality:

2-(DIPHENYLPHOSPHINO)-1,3-BENZOTHIAZOLE 95.00% ^*data from reagent suppliers

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

Technology Process of 2-(DIPHENYLPHOSPHINO)-1,3-BENZOTHIAZOLE

There total 5 articles about 2-(DIPHENYLPHOSPHINO)-1,3-BENZOTHIAZOLE which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 79.0%

1,3-Benzothiazole (95-16-9) + chloro-diphenylphosphine (1079-66-9,74391-44-9) → 2-(diphenylphosphanyl)benzo[d]thiazole (80679-26-1)

Guidance literature:

1,3-Benzothiazole; With (TMP)2Zn*2MgCl₂*2LiCl; In tetrahydrofuran; at 25 ℃; for 0.5h;

chloro-diphenylphosphine; In tetrahydrofuran; at 25 ℃; for 5h; Further stages.;

DOI:10.1002/anie.200701984

Reference yield: 76.0%

2-(trimethylsilyl)benzothiazole (32137-73-8) + chloro-diphenylphosphine (1079-66-9,74391-44-9) → 2-(diphenylphosphanyl)benzo[d]thiazole (80679-26-1)

Guidance literature:

1.) RT, 2 h, 2.) 60 deg C, 30 min, 3.) 100-110 deg C, 10 h;

DOI:10.1021/jo00347a023

Reference yield: 60.0%

bbenzo[d]thiazol-2-yldiphenylphosphine oxide (720675-16-1) → 2-(diphenylphosphanyl)benzo[d]thiazole (80679-26-1)

Guidance literature:

With copper(II) bis(trifluoromethanesulfonate); 1,1,3,3-tetramethyldisilazane; In toluene; at 100 ℃; for 24h; Sealed tube; Inert atmosphere;

DOI:10.1039/c4cc10017d

upstream raw materials:

2-(trimethylsilyl)benzothiazole

chloro-diphenylphosphine

1,3-Benzothiazole

lithium diphenylphosphide

Downstream raw materials:

[(2-(diphenylphosphino)benzo[d]thiazole)₃Cu₂I₂]

Refernces

• 1、 Zink, Daniel M.,B?chle, Michael,Baumann, Thomas,Nieger, Martin,Kühn, Michael,Wang, Cong,Klopper, Wim,Monkowius, Uwe,Hofbeck, Thomas,Yersin, Hartmut,Br?se, Stefan. "Synthesis, structure, and characterization of dinuclear copper(I) halide complexes with P^N ligands featuring exciting photoluminescence properties". . p. 2292 - 2305. Retrieved 2013/04/10.
• 2、 Moore, Stephen S.,Whitesides, George M.. "Synthesis and Coordinating Properties of Heterocyclic-Substituted Tertiary Phosphines". . p. 1489 - 1493. Retrieved 2007/10/02.