1-phenyl-2-iodo-1,2-dicarba-closo-dodecaborane

Base Information

• Chemical Name: 1-phenyl-2-iodo-1,2-dicarba-closo-dodecaborane
• CAS No.: 20347-50-6
• Molecular Formula: C₈H₁₅B₁₀I
• Molecular Weight: 346.222
• Mol file: 20347-50-6.mol

Synonyms:1-phenyl-2-iodo-1,2-dicarba-closo-dodecaborane

Chemical Property of 1-phenyl-2-iodo-1,2-dicarba-closo-dodecaborane

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of 1-phenyl-2-iodo-1,2-dicarba-closo-dodecaborane

There total 2 articles about 1-phenyl-2-iodo-1,2-dicarba-closo-dodecaborane which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 71.0%

1-phenyl-1,2-closo-C2B10H11 (16390-61-7) + iodine (7553-56-2,12190-71-5,8031-47-8) → 1-phenyl-2-iodo-1,2-dicarba-closo-dodecaborane (20347-50-6)

Guidance literature:

With n-BiLi; In diethyl ether; hexane; under N2; soln. of n-BuLi in n-hexane added dropwise to stirring soln. of B compd. in Et2O at 0°C; stirred at room temp. for 0.5 h; cooled to 0°C; I2 added; stirred at 0°C for 30 min and at room temp. for 30 min; extd. with aq. Na2S2O3; washed with H2O; org. phase dried (MgSO4); filtered; evapd. in vac.; purified by flash chromy. at -10°C under Ar (silica gel, Et2O); elem. anal.;

DOI:10.1021/om900443v

Reference yield:

bis(phenyl-o-carboranyl)mercury (17141-29-6) + iodine (7553-56-2,12190-71-5,8031-47-8) → 1-phenyl-2-iodo-1,2-dicarba-closo-dodecaborane (20347-50-6)

Guidance literature:

With {(C₄H₉)4N}I;

Reference yield: 90.0%

1-phenyl-2-iodo-1,2-dicarba-closo-dodecaborane (20347-50-6) + 1,4-dimethoxybezene (150-78-7) → C16H24B10O2

Guidance literature:

With sodium carbonate; In dichloromethane; at 20 ℃; for 48h; Inert atmosphere; UV-irradiation; Schlenk technique;

DOI:10.1002/anie.201610810

upstream raw materials:

bis(phenyl-o-carboranyl)mercury

iodine

1-phenyl-1,2-closo-C₂B₁₀H₁₁

Downstream raw materials:

1-phenyl-1,2-closo-C₂B₁₀H₁₁

W(CO)5(PIClC₅(CH₃)5)

C₁₅H₁₉B₁₀FO

1-CO(C₆H₄-4-OCH₃)-2-C₆H₅-1.2-C₂B₁₀H₁₀

Refernces

• 1、 Streubel, Rainer,Oezbolat-Schoen, Aysel,Bode, Maren,Daniels, Joerg,Schnakenburg, Gregor,Teixidor, Francesc,Vinas, Clara,Vaca, Albert,Pepiol, Ariadna,Farras, Pau. "Investigations on the reactivity of Li/Cl phosphinidenoid tungsten complexes toward various iodine compounds". . p. 6031 - 6035. Retrieved 2010/03/04.