cis-hydrido(3,5-dimethylbenzyl){bis(dicyclohexylphosphino)ethane}platinum(II)

Base Information

• Chemical Name: cis-hydrido(3,5-dimethylbenzyl){bis(dicyclohexylphosphino)ethane}platinum(II)
• CAS No.: 105373-24-8
• Molecular Formula: C₃₅H₆₀P₂Pt
• Molecular Weight: 737.889
• Mol file: 105373-24-8.mol

Synonyms:cis-hydrido(3,5-dimethylbenzyl){bis(dicyclohexylphosphino)ethane}platinum(II)

Chemical Property of cis-hydrido(3,5-dimethylbenzyl){bis(dicyclohexylphosphino)ethane}platinum(II)

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of cis-hydrido(3,5-dimethylbenzyl){bis(dicyclohexylphosphino)ethane}platinum(II)

There total 3 articles about cis-hydrido(3,5-dimethylbenzyl){bis(dicyclohexylphosphino)ethane}platinum(II) which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 82.0%

cis-[bis-(dicyclohexylphosphino)ethane]hydridoneopentylplatinum(II) + 1,3,5-trimethyl-benzene (108-67-8) → cis-hydrido(3,5-dimethylbenzyl){bis(dicyclohexylphosphino)ethane}platinum(II) (105373-24-8) + cis-hydrido(2,4,6-trimethylphenyl){bis(dicyclohexylphosphino)ethane}platinum(II) (105373-23-7)

Guidance literature:

In 1,2,5-trimethyl-benzene; thermolysis of cis-hydridoneopentyl{bis(dicyclohexylphosphino)ethane}platinum(II) in mesitylene via supposed {bis(dicyclohexylphosphino)ethane}platinum(0) at 69°C for 4.2 h , equilibrating after about 40 h heating; Kinetics;

DOI:10.1021/ja00213a016

Reference yield: 34.0%

cis-chloro(3,5-dimethylbenzyl){bis(dicyclohexylphosphino)ethane}platinum(II) (111848-64-7) → cis-hydrido(3,5-dimethylbenzyl){bis(dicyclohexylphosphino)ethane}platinum(II) (105373-24-8)

Guidance literature:

With Na{HB(OMe)3}; In tetrahydrofuran; treating cis-chloro(3,5-dimethylbenzyl){bis(dicyclohexylphosphino)ethane}platinum(II) with NaHB(OMe)3 in THF became cloudy, after 1 h at room temp. quenched by H2O at 0°C; ether added, org. layer sepd., aq. layer extd. with ether, evapd., resulting oil dissolved in minimum THF, 1 part MeOH added, crystn. at -10°C, once recrystd., suction filtrn.;

DOI:10.1021/ja00213a016

Reference yield:

cis-{bis(dicyclohexylphosphino)ethane}chloroneopentylplatinum(II) → cis-hydrido(3,5-dimethylbenzyl){bis(dicyclohexylphosphino)ethane}platinum(II) (105373-24-8) + cis-hydrido(2,4,6-trimethylphenyl){bis(dicyclohexylphosphino)ethane}platinum(II) (105373-23-7)

Guidance literature:

Multi-step reaction with 2 steps

1: tetrahydrofuran

2: 1,3,5-trimethyl-benzene

In tetrahydrofuran; 1,3,5-trimethyl-benzene;

DOI:10.1021/ja00285a039

upstream raw materials:

cis-chloro(3,5-dimethylbenzyl){bis(dicyclohexylphosphino)ethane}platinum(II)

1,3,5-trimethyl-benzene

Refernces