bis(triphenylphosphine)carbonateplatinum(II)

Base Information

• Chemical Name: bis(triphenylphosphine)carbonateplatinum(II)
• CAS No.: 17030-86-3
• Molecular Formula: C₃₇H₃₀O₃P₂Pt
• Molecular Weight: 779.671
• Mol file: 17030-86-3.mol

Synonyms:bis(triphenylphosphine)carbonateplatinum(II)

Chemical Property of bis(triphenylphosphine)carbonateplatinum(II)

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of bis(triphenylphosphine)carbonateplatinum(II)

There total 20 articles about bis(triphenylphosphine)carbonateplatinum(II) which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 83.0%

Pt((C6H5)3P)2(OOH)(CH3C6H4O) (131006-50-3) → bis(triphenylphosphine)carbonateplatinum(II) (17030-86-3)

Guidance literature:

With carbon dioxide; In benzene; byproducts: p-MeC6H4OH, (C6H5)3PO; After 2 min of bubbling CO2 through benzene the platinum peroxide complex was added and the suspn. heated at 50°C for 6 h.; filtn., evapn. to dryness, IR, (1)H-NMR and thin-layer chromy. of the residue; manipulations under N2;

DOI:10.1016/S0020-1693(00)80218-2

Reference yield: 71.0%

bis(triphenylphosphine)platinum(II) dichloride (10199-34-5,14056-88-3,15604-36-1) + silver carbonate → bis(triphenylphosphine)carbonateplatinum(II) (17030-86-3)

Guidance literature:

With water; In dichloromethane; Ar-atmosphere, protection from light; equimolar amts., stirring in wet CH2Cl2 for several h (NMR monitoring); filtration, pptn. on hexane addn.;

DOI:10.1021/ic9603159

Reference yield: 71.0%

cis-Pt(1-pentenyl)2(triphenylphosphine)2 (864370-43-4) + carbon dioxide (124-38-9,18923-20-1) + water (7732-18-5) → bis(triphenylphosphine)carbonateplatinum(II) (17030-86-3)

Guidance literature:

In toluene; CO2 bubbled through soln. of Pt complex in wet toluene for 5-6 min, soln. stirrred at 50°C under CO2 for 72 h; solvent removed under vac., residue washed with Et2O, solid filtered off, recrystd. from CH2Cl2/hexane (2/1);

DOI:10.1016/j.ica.2010.06.026

upstream raw materials:

cis-dichlorobis(triphenylphosphine)platinum(II)

potassium carbonate

triphenylphosphine

platinum(II) chloride

Downstream raw materials:

(P(C₆H₅)3)2Pt(HCO₃)⁽¹⁺⁾*HC(SO₂CF₃)2^(1-)=(P(C₆H₅)3)2Pt(HCO₃)(HC(SO₂CF₃)2)

[Pt(C₆O₂H₄(OH)2(O)O₂)(P(C₆H₅)3)2]

cis-[Pt(O₂CCF₃)2(PPh₃)2]

Refernces

• 1、 Sivaramakrishna, Akella,Moss, John R.,Su, Hong. "Novel reactivity aspects of cis-bis(1-alkenyl)platinum(II) compounds of the type Pt(CH2(CH2)nCHCH2) 2L2 (where L2 = dppp, dppe, dppm and n = 1, 2)". . p. 3345 - 3350. Retrieved 2011/02/16.
• 2、 Mochida, Kunio,Karube, Hironori,Nanjo, Masato,Nakadaira, Yasuhiro. "Preparation and structural characterization of 1,4-digerma-2-buten-1,4- diylplatinum(II) complexes and their reactions with alkynes, carbon monoxide, and isocyanides". . p. 4734 - 4741. Retrieved 2008/10/09.